36342-11-7

Basic information

• Product Name: 3-CHLORO-1-PHENYLPYRROLIDINE-2,5-DIONE
• Synonyms: ART-CHEM-BB B023325;AKOS BBS-00002202;3-CHLORO-1-PHENYLPYRROLIDINE-2,5-DIONE
• CAS NO: 36342-11-7
• Molecular Formula: C₁₀H₈ClNO₂
• Molecular Weight: 209.63
• Mol File: 36342-11-7.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 438.8°Cat760mmHg
• Flash Point: 219.2°C
• Appearance: /
• Density: 1.39g/cm³
• Vapor Pressure: 6.73E-08mmHg at 25°C
• Refractive Index: 1.611
• CAS DataBase Reference: 3-CHLORO-1-PHENYLPYRROLIDINE-2,5-DIONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-CHLORO-1-PHENYLPYRROLIDINE-2,5-DIONE(36342-11-7)
• EPA Substance Registry System: 3-CHLORO-1-PHENYLPYRROLIDINE-2,5-DIONE(36342-11-7)

Safety Data

• Hazardous Substances Data: 36342-11-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H8ClNO2/c11-8-6-9(13)12(10(8)14)7-4-2-1-3-5-7/h1-5,8H,6H2

Upstream product

• 37902-58-2 3-phenylcarbamoylacrylic acid 
• 75-36-5 acetyl chloride 
• 555-59-9 N-phenylmaleamic acid 
• 108-31-6 maleic anhydride 
• 75-44-5 phosgene 
• 68-12-2 N,N-dimethyl-formamide 
• 62-53-3 aniline 
• 941-69-5 N-phenyl-maleimide 

Downstream Products

• 941-69-5 N-phenyl-maleimide 
• 83-25-0 N-phenylmaleimide 

Relevant articles and documents

Regioselective hetero-Michael addition of oxygen, sulfur, and nitrogen nucleophiles to maleimides catalyzed by BF3·OEt2

Abstract A practical BF3·OEt2-catalyzed regioselective 1,2-addition or 1,4-hetero-Michael addition of oxygen, sulfur, and nitrogen nucleo philes to maleimides has been developed for the synthesis of alkyl fumarate derivatives or 3-su

α-chlorosuccinimides - A new source for maleimides and succinimides

N-Arylmaleimides and N-arylsuccinimides were prepared by dehydrochlorination reaction of N-aryl α-chlorosuccinimides in the presence of a base and by reduction of 2-chlorosuccinimide in the presence of zinc, respectively. N-Aryl α-chlorosuccinimides were obtained by dehydration of N-aryl substituted maleamic acids in the presence of thionyl chloride. The structure of the synthesized compounds was confirmed by IR, 1H-NMR and 13C-NMR spectra.

Preparation process of N-substituted monochlorosuccinimides

N-substituted monochlorosuccinimides e.g., N-phenylmonochlorosuccinimide, can be prepared in a high yield by reacting a maleamic acid, e.g., N-phenylmaleamic acid, with phosgene in the presence of a catalyst, e.g., dimethylformamide.