36395-57-0Relevant articles and documents
Synthesis and solid-state structures of new cyclophane host molecules
Czech, Bronislaw P.,Kus, Piotr,Stetson, Christopher M.,Dalley, N. Kent,Bartsch, Richard A.
, p. 1360 - 1365 (2007/10/03)
Five new cyclophane host molecules (corrals) are prepared by linking together two α,α′-di(4-hydroxyphenyl)-1,4-diisopropylbenzene or α,α′-di(3,5-dimethyl-4-hydroxyphenyl)-1,4-diisopropylbenzene units with two permethylene spacers. Three small cyclophane hosts (boxes) are synthesized by cyclization of α,α′-di(4-hydroxyphenyl)-1,4-diisopropylbenzene with di(bromomethyl)benzene compounds. Solid-state structures of one corral and one box are reported.
Synthese symmetrischer, makrocyclischer phosphoramidite
Bauer,Habicher,Jones,Thoennessen,Schmutzler
, p. 19 - 31 (2007/10/03)
The reaction of phosphorous ester diamide 1 with bisphenol 2 did not lead to the expected asymmetric macrocycle 3 but instead in low yield to the symmetric macrocycle 4. The structure of the trans-isomer of 4 was determined by X-ray diffractometry. The same phenomenon was observed in the reaction of phosphorous ester diamide 5 with bisphenol 6, affording the symmetric macrocycle 7 as a mixture of cis-and trans-isomers. These results can only be explained by transesterification reactions which occur prior to the esterification of the phosphorous amide function.