36405-47-7

Basic information

• Product Name: 2,2,3,4,4,4-Hexafluorobutyl methacrylate
• Synonyms: 2,2,3,4,4,4-HEXAFLUOROBUTYL METHACRYLATE;1H,1H,3H-HEXAFLUOROBUTYL METHACRYLATE;DAIKIN M-7310;2-METHYL-ACRYLIC ACID 2,2,3,4,4,4-HEXAFLUORO-BUTYL ESTER;methacrylic acid 2,2,3,4,4,4-hexafluorobutyl ester;2,2,3,4,4,4-Hexafluorobutyl methacrylate 99%;2,2,3,4,4,4-Hexafluorobutylmethacrylate99%;2-Propenoic acid,2-methyl-,2,2,3,4,4,4-hexafluorobuthyl ester
• CAS NO: 36405-47-7
• Molecular Formula: C8H8F6O2
• Molecular Weight: 250.14
• EINECS: -0
• Product Categories: monomer;C8 to C9Monomers;Fluorine-Containing Monomers for 157 nm UV Lithography Resist PolymersPhotonic and Optical Materials;Low Refractive Index Monomers;Acrylic Monomers;Carbonyl Compounds;Esters;Fluorinated AcrylicsSelf Assembly&Contact Printing;Lithography Monomers;Waveguide Materials;Acrylic Monomers;Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Contact Printing;Fluorinated Acrylics;Fluorine-Containing Monomers for 157 nm UV Lithography Resist Polymers;Lithography Monomers;Low Refractive Index Monomers;Materials Science;Micro/NanoElectronics;Monomers;Organic and Printed Electronics;Organic Building Blocks;Photonic and Optical Materials;Polymer Science;Self Assembly &Waveguide Materials
• Mol File: 36405-47-7.mol
• Article Data: 0

Chemical Properties

• Boiling Point: 158 °C(lit.)
• Flash Point: 134 °F
• Appearance: clear colorless liquid
• Density: 1.348 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.25 psi ( 20 °C)
• Refractive Index: n20/D 1.361(lit.)
• Storage Temp.: 0-6°C
• Water Solubility: Difficult to mix in water.
• Sensitive: Lachrymatory
• BRN: 2725177
• CAS DataBase Reference: 2,2,3,4,4,4-Hexafluorobutyl methacrylate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,3,4,4,4-Hexafluorobutyl methacrylate(36405-47-7)
• EPA Substance Registry System: 2,2,3,4,4,4-Hexafluorobutyl methacrylate(36405-47-7)

Safety Data

• Hazard Codes: Xi,F
• Statements: 36/37/38
• Safety Statements: 26-27-36/37/39-37/39
• RIDADR: UN 3272 3/PG 3
• WGK Germany: 3
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 36405-47-7(Hazardous Substances Data)

Usage

Description

2,2,3,4,4,4-Hexafluorobutyl methacrylate (HFBMA) is a fluorinated monomer that is used in the synthesis of well-defined organic/inorganic hybrid fluorinated star polymers. It possesses unique properties due to the presence of fluorine atoms, which contribute to its chemical stability, low surface energy, and high thermal resistance.

Uses

Used in Coatings Industry:
2,2,3,4,4,4-Hexafluorobutyl methacrylate is used as an epoxy thinner and as a modifier for (meth)acrylate resins. Its incorporation into these resins enhances their properties, such as chemical resistance, adhesion, and durability, making them suitable for various coating applications.
Used in Polymer Synthesis:
2,2,3,4,4,4-Hexafluorobutyl methacrylate is used as a monomer in the synthesis of well-defined organic/inorganic hybrid fluorinated star polymers via atom transfer radical polymerization (ATRP). The use of octa(aminophenyl)silsesquioxane (OAPS) nano-cage as an initiator allows for the creation of these star polymers with controlled molecular architecture and improved properties.
These star polymers have potential applications in various fields, such as high-performance materials, biomaterials, and drug delivery systems, due to their unique structure and properties derived from the incorporation of fluorine atoms and the hybrid organic/inorganic nature of the polymers.

InChI:InChI=1/C8H8F6O2/c1-4(2)5(15)16-3-7(10,11)6(9)8(12,13)14/h6H,1,3H2,2H3/t6-/m1/s1