36629-42-2 Usage
Description
Methyl Pentafluorobenzoate is a clear colorless to light yellow liquid that is utilized in various applications due to its unique chemical properties. It is a derivative of benzoic acid with a methyl and a pentafluoro group attached, which contributes to its reactivity and stability in different chemical processes.
Uses
Used in Photocoupling Applications:
Methyl Pentafluorobenzoate is used as a key component in the preparation of photocoupling agents. It is particularly useful for the efficient immobilization of polymers, nanoparticles, graphene, and small molecules. Its chemical structure allows for strong interactions with these materials, enhancing their stability and functionality.
Used in Photoactive Reagent Preparation:
Methyl Pentafluorobenzoate is also employed in the preparation of photoactive reagent N-hydroxysuccinimide (NHS)-PFPA. This reagent is valuable in various chemical reactions, particularly in the field of biochemistry and pharmaceuticals, where it can be used for the conjugation of molecules to create new compounds with specific properties.
Used in Chemical Synthesis:
In the chemical synthesis industry, Methyl Pentafluorobenzoate serves as an important intermediate for the production of various compounds. Its unique structure and reactivity make it a versatile building block for creating a wide range of molecules with different applications.
Used in Material Science:
Methyl Pentafluorobenzoate is utilized in the development of new materials with specific properties, such as improved stability, reactivity, or functionality. Its incorporation into polymers, nanoparticles, and other materials can enhance their performance in various applications, including electronics, coatings, and adhesives.
Check Digit Verification of cas no
The CAS Registry Mumber 36629-42-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,6,2 and 9 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 36629-42:
(7*3)+(6*6)+(5*6)+(4*2)+(3*9)+(2*4)+(1*2)=132
132 % 10 = 2
So 36629-42-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H3F5O2/c1-15-8(14)2-3(9)5(11)7(13)6(12)4(2)10/h1H3
36629-42-2Relevant articles and documents
Study of Pd-elimination under carbonylation conditions: Regioselective formation of esters
Albeniz, Ana C.,Espinet, Pablo,Lin, Yong-Shou
, p. 13851 - 13866 (1998)
The regioselective synthesis of methyl esters is achieved by carbonylation of two different types of organometallic derivatives resulting from insertion of non-conjugated dienes into a Pd-aryl bond. When the diene and the Pd-aryl synthon [PdPfBr(NCMe)2] (Pf = C6F5) are mixed at low temperature, solutions of η1-η2-enylpalladium complexes can be isolated and converted into β-aryl methyl esters by reaction with CO in the presence of methanolic solutions of sodium methoxide. When the reactions are carried out at room temperature η3-allylpalladium complexes are isolated, and their carbonylation gives β,γ-unsaturated esters.
SOLID FORMS OF AN FGFR INHIBITOR AND PROCESSES FOR PREPARING THE SAME
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Page/Page column 92-93, (2019/11/19)
The present disclosure relates to 3-(2,6-difluoro-3,5-dimethoxyphenyl)-1-ethyl-8-(morpholin-4-ylmethyl)-1,3,4,7-tetrahydro-2H-pyrrolo[3',2':5,6]pyrido[4,3-d]pyrimidin-2-one, solid forms and polymorphs thereof, methods of preparation thereof, and intermediates in the preparation thereof, which are useful in the treatment of the FGFR-associated or mediated diseases such as cancer.
Photocatalytic hydrodefluorination: Facile access to partially fluorinated aromatics
Senaweera, Sameera M.,Singh, Anuradha,Weaver, Jimmie D.
supporting information, p. 3002 - 3005 (2014/03/21)
Polyfluorinated aromatics are essential to materials science as well as the pharmaceutical and agrochemical industries and yet are often difficult to access. This Communication describes a photocatalytic hydrodefluorination approach which begins with easily accessible perfluoroarenes and selectively reduces the C-F bonds. The method allows facile access to a number of partially fluorinated arenes and takes place with unprecedented catalytic activity using a safe and inexpensive amine as the reductant.
