36707-32-1

Basic information

• Product Name: alfa-phenylethylnaphthalene
• CAS NO: 36707-32-1
• Molecular Weight: 232.325
• Mol File: 36707-32-1.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: alfa-phenylethylnaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: alfa-phenylethylnaphthalene(36707-32-1)
• EPA Substance Registry System: alfa-phenylethylnaphthalene(36707-32-1)

Safety Data

• Hazardous Substances Data: 36707-32-1(Hazardous Substances Data)

Usage

Chemical compound

Alfa-phenylethylnaphthalene

Family

Naphthalenes

Physical state

White solid

Odor

Distinct floral

Main application

Production of fragrances and perfumes

Characteristics

Long-lasting scent

Uses

High-end perfumes, colognes, air fresheners, scented candles

Other applications

Intermediate in chemical synthesis, plasticizer

Upstream product

• 2039-70-5 (E)-2-styrylnaphthalene 
• 90-11-9 1-Bromonaphthalene 
• 34420-17-2 (2-phenylethyl)boronic acid 
• 91-20-3 naphthalene 
• 103-80-0 phenylacetyl chloride 
• 91-60-1 2-Naphthalenethiol 
• 4780-79-4 1-naphthalene methanol 
• 100-42-5 styrene 
• 622-24-2 2-phenylethyl chloride 
• 703-55-9 1-naphthylmagnesiumbromide 
• 3277-89-2 phenethylmagnesium bromide 
• 68211-49-4 1-naphthyl tosylate 
• 71912-48-6 4-phenethyl-1,2-dihydronaphthalene 
• 4044-57-9 1-phenylethynyl-naphthalene 

Downstream Products

• 72035-50-8 3-(naphthalen-1-yl)-2-phenylpropanenitrile 
• 218-01-9 chrysene 

Relevant articles and documents

"bulky-Yet-Flexible" α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air

To pursue a highly regioselective and efficient reductive Heck reaction, a series of moisture-and air-stable α-diimine palladium precatalysts were rationally designed, readily synthesized, and fully characterized. The relationship between the structures of the palladium complexes and the catalytic properties was investigated. It was revealed that the"bulky-yet-flexible"palladium complexes allowed highly anti-Markovnikov-selective hydroarylation of alkenes with (hetero)aryl bromides under aerobic conditions. Further synthetic application of the present protocol could provide rapid and straightforward access to functional and biologically active molecules.

Application of novel coupling reaction to preparing carbon-carbon bond structured compounds

The invention relates to application of a novel coupling reaction to preparing carbon-carbon bond structured compounds and mainly provides a reaction between alkyl indium compounds and halides. The reaction between the alkyl indium compounds and the halides can produce corresponding carbon-carbon structured products. The novel coupling reaction is high in process yield, broad in functional group tolerance and good in compatibility.

Preparation of Alkyl Indium Reagents by Iodine-Catalyzed Direct Indium Insertion and Their Applications in Cross-Coupling Reactions

An efficient method for the synthesis of alkyl indium reagent by means of an iodine-catalyzed direct indium insertion into alkyl iodide in THF is reported. The thus-generated alkyl indium reagents effectively underwent Pd-catalyzed cross-coupling reactions with various aryl halides, exhibiting good compatibility to a variety of sensitive functional groups. By replacing THF with DMA and using 0.75 equiv of iodine, less reactive alkyl bromide could be used as substrate for indium insertion with equal ease.