367507-35-5

Basic information

• Product Name: 1,2-Pyrrolidinedicarboxylic acid, 4-(phenylseleno)-, 1-(1,1-dimethylethyl) 2-ethyl ester, (2S,4S)-
• CAS NO: 367507-35-5
• Molecular Formula: C18H25NO4Se
• Molecular Weight: 398.361
• Mol File: 367507-35-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-Pyrrolidinedicarboxylic acid, 4-(phenylseleno)-, 1-(1,1-dimethylethyl) 2-ethyl ester, (2S,4S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Pyrrolidinedicarboxylic acid, 4-(phenylseleno)-, 1-(1,1-dimethylethyl) 2-ethyl ester, (2S,4S)-(367507-35-5)
• EPA Substance Registry System: 1,2-Pyrrolidinedicarboxylic acid, 4-(phenylseleno)-, 1-(1,1-dimethylethyl) 2-ethyl ester, (2S,4S)-(367507-35-5)

Safety Data

• Hazardous Substances Data: 367507-35-5(Hazardous Substances Data)

Upstream product

• 51-35-4 4R-4-hydroxyproline 
• 74844-91-0 1-tert-butyl 2-methyl (2S,4R)-4-hydroxy-1,2-pyrrolidinedicarboxylate 
• 40216-83-9 L-4-hydroxyproline methyl ester hydrochloride 
• 24424-99-5 di-tert-butyl dicarbonate 
• 1666-13-3 diphenyl diselenide 
• 84520-67-2 (2S,4R)-4-(methylsulfonyloxy)pyrrolidine-1,2-dicarboxylic acid 1-tert-butylester-2-methylester 

Downstream Products

• 571201-15-5 (S)-5,7a-dihydro-1H-pyrrolo[1,2-c]oxazol-3-one 

Relevant articles and documents

Studies towards a total synthesis of kainic acid

The preparation of the fused bicycle 14 is reported together with its photocyclisation to the dioxinone 2. Base induced fragmentation of the photoadduct 15 formed exclusively in the aforementioned photocylisation, followed by Wittig methylenation gave the kainoid derivative 18.