36809-23-1Relevant articles and documents
Synthesis of two novel dinuclear palladium(I) complexes and studies of their catalytic activity in amination reactions
Christmann, Ute,Vilar, Ramon,White, Andrew J. P.,Williams, David J.
, p. 1294 - 1295 (2004)
Two novel palladium(I) dinuclear complexes have been prepared and their structural characterization has revealed an unprecedented μ2- η3:η3 coordination between a phenyl ring from PtBu2Bph (Bph = Biphenyl) and the PdI-Pd I unit present in the complexes.
Tuning the Donor-π-Acceptor Character of Arylborane-Arylamine Macrocycles
Baser-Kirazli, Nurcan,Lalancette, Roger A.,J?kle, Frieder
supporting information, p. 520 - 528 (2021/02/27)
Donor-π-acceptor compounds based on arylamine and arylborane moieties connected by a π-conjugated linker are attractive materials in organic electronics and imaging applications due to the strong charge transfer character that leads to low energy absorption and solvatochromic emission properties. Here we introduce a new conjugated macrocyclic system that consists of four arylborane and two arylamine units as confirmed by single-crystal X-ray structure analysis. The acceptor character of the arylboranes is enhanced by exocyclic electron-withdrawing 2,4,6-tris(trifluoromethyl)phenyl (FMes) substituent as well as the mutual interaction between adjacent boranes. The absorption, solvent-dependent emission, and electrochemical properties are studied and compared to those of other macrocyclic organoboranes. Computational studies offer additional insights into the electronic structure. Due to the enhanced acceptor character of the boranes, the LUMO orbitals are lower lying, leading to more facile reduction, red-shifted absorption and emission, and larger Stokes shifts than those found for previously studied B-N macrocycles.
(DiMeIHeptCl)Pd: A Low-Load Catalyst for Solvent-Free (Melt) Amination
Semeniuchenko, Volodymyr,Sharif, Sepideh,Day, Jonathan,Chandrasoma, Nalin,Pietro, William J.,Manthorpe, Jeffrey,Braje, Wilfried M.,Organ, Michael G.
, p. 10343 - 10359 (2021/07/31)
(DiMeIHeptCl)Pd, a hyper-branched N-aryl Pd NHC catalyst, has been shown to be efficient at performing amine arylation reactions in solvent-free ("melt") conditions. The highly lipophilic environment of the alkyl chains flanking the Pd center serves as lubricant to allow the complex to navigate through the paste-like environment of these mixtures. The protocol can be used on a multi-gram scale to make a variety of aniline derivatives, including substrates containing alcohol moieties.
Transition-Metal-Free Diarylation of Isocyanates with Arynes
Jang, Woo Cheol,Hwang, Dong Wook,Seo, Jeong Hoon,Ko, Haye Min
supporting information, (2019/08/30)
A facile method for the transition-metal-free diarylation of isocyanates with arynes in the presence of cesium fluoride has been developed, which affords functionalized diaryl amines in moderate to excellent yields. This reaction has good functional group tolerance and provides excellent regioselectivity by utilizing a methoxy-substituted aryne precursor.