37067-45-1

Basic information

• Product Name: N¹,S-Dimethylthiobenzohydrazoniumiodid
• Synonyms: N¹,S-Dimethylthiobenzohydrazoniumiodid
• CAS NO: 37067-45-1
• Molecular Weight: 308.186
• Mol File: 37067-45-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N¹,S-Dimethylthiobenzohydrazoniumiodid(CAS DataBase Reference)
• NIST Chemistry Reference: N¹,S-Dimethylthiobenzohydrazoniumiodid(37067-45-1)
• EPA Substance Registry System: N¹,S-Dimethylthiobenzohydrazoniumiodid(37067-45-1)

Safety Data

• Hazardous Substances Data: 37067-45-1(Hazardous Substances Data)

Upstream product

• 21048-05-5 N-methylbenzothiohydrazide 
• 74-88-4 methyl iodide 

Downstream Products

• 83274-35-5 4,6-Dihydro-1-methyl-3-phenyl-1H-cyclopenta-1,2,4-triazin-5,7-dicarbonsaeure-dimethylester 
• 83274-36-6 1-Methyl-3-phenyl-1H-cyclopenta-1,2,4-triazin-5,7-dicarbonsaeure-dimethylester 
• 83274-37-7 2-Methyl-3-phenyl-2H-cyclopenta-1,2,4-triazin-5,7-dicarbonsaeure-dimethylester 
• 29945-53-7 1-methyl-5-phenyl-1H-1,2,4-triazole 
• 39696-58-7 1-methyl-3-phenyl-1H-1,2,4-triazole 
• 137257-26-2 3,3'-Methylenbis(1,2,3,4-tetrahydro-1,3-dimethyl-6-phenyl-1,2,4,5-tetrazin) 
• 137256-78-1 C₈H₁₂N₄*2ClH 
• 137257-21-7 1-Methyl-3,6-diphenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazine-3-carboxylic acid methyl ester 
• 137257-46-6 2-Methyl-3-phenyl-1,10b-dihydro-2H-[1,2,4,5]tetrazino[6,1-a]isoindol-6-one 
• 137257-38-6 7,8-Dichloro-2-methyl-3-phenyl-1,8a-dihydro-2H-pyrrolo[1,2-b][1,2,4,5]tetrazin-6-one 
• 137257-33-1 2-Methyl-3-phenyl-2H-[1,2,4,5]tetrazino[6,1-a]isoindol-6-one 
• 137257-22-8 (1,3-Dimethyl-6-phenyl-1,2,3,4-tetrahydro-[1,2,4,5]tetrazin-3-yl)-phenyl-methanone 
• 137257-17-1 1,2,3,4-Tetrahydro-3-(4-methoxyphenyl)-1-methyl-6-phenyl-1,2,4,5-tetrazin 
• 137257-16-0 3,3,9-Trimethyl-8-phenyl-6,7,9,10-tetraaza-spiro[4.5]dec-7-en-1-one 

Relevant articles and documents

Hydrazidines, V. - Synthesis and Reactions of Aromatic and Aliphatic Hydrazidines and Their N1-Substituted Derivatives

Aromatic hydrazidines 3 have been synthetized by reaction of aromatic orthocarboxylates 4 with tert-butyl carbazate (5) and reaction of the protected hydrazidines 7 with HCl/methanol or HBr/acetic acid.Aliphatic N1-methylhydrazidines 8 have been prepared by methylation of bis (tert-butoxycarbonyl)-hydrazidines 7 and deprotection with HBr/acetic acid.Aromatic N1-methylhydrazidines 8 have been obtained by methylation of N1-methyl(thiohydrazides) 11, reaction of 12 with tert-butyl carbazate (5) and deprotection of 13 with HCl/methanol. -- Attempts to remove both protecting groups in N1-alkyl-N2,N4-bis(benzylidene)hydrazidines 16 failed. -- Some reactions of 3 and 8 are described.Key Words: Hydrazidines / 1,2,4-Triazines / 1,2,4,5-Tetrazines / 1,2,4,5-Tetrazinoisoindoles / Pyrrolo1,2,4,5-tetrazines