37118-22-2Relevant articles and documents
Cu-Catalyzed Oxidative-Reaction of Tosylmethylisocyanide and Benzyl Alcohols: Efficient Synthesis of 4-(tert-butylperoxy)-5-aryloxazol-2(3H)-ones and 5-Aryloxazol-2(5H)-ones
Sepahvand, Heshmatollah,Bazgir, Ayoob,Shaabani, Ahmad
, p. 2068 - 2075 (2020/01/28)
Herein, a novel copper-catalyzed reaction of tosylmethylisocyanide (TosMIC) with benzyl alcohols has been developed using tert-butyl hydroperoxide (TBHP) for the first time. The reaction involves the in-situ oxidation of benzyl alcohol to corresponding be
A Mild and convenient synthesis of 4-tosyl-4,5-dihydrooxazoles
Companyo, Xavier,Moyano, Albert,Rios, Ramon
experimental part, p. 293 - 296 (2010/04/23)
A facile and mild synthesis of 4-tosyl-4,5-dihydrooxazoles is described. The reaction between tosyl methyl isocyanide (TosMIC) and cinnamic or aromatic aldehydes is catalyzed by triethylamine, affording trans-5-styryl- or 5-aryl-4-tosyl-4,5-dihydrooxazole