37527-56-3

Basic information

• Product Name: diethyl 1,1':4',1''-terphenyl-4,4''-dicarboxylate
• Synonyms: diethyl 1,1':4',1''-terphenyl-4,4''-dicarboxylate
• CAS NO: 37527-56-3
• Molecular Weight: 374.436
• Mol File: 37527-56-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl 1,1':4',1''-terphenyl-4,4''-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 1,1':4',1''-terphenyl-4,4''-dicarboxylate(37527-56-3)
• EPA Substance Registry System: diethyl 1,1':4',1''-terphenyl-4,4''-dicarboxylate(37527-56-3)

Safety Data

• Hazardous Substances Data: 37527-56-3(Hazardous Substances Data)

Upstream product

• 624-38-4 para-diiodobenzene 
• 131379-16-3 4-(ethoxycarbonyl)phenylzinc iodide 

Relevant articles and documents

Palladium-catalyzed synthesis of biaryls from arylzinc compounds using N-chlorosuccinimide or oxygen as an oxidant

In the presence of a catalytic amount of Pd2+ or Pd0, oxidative homo-coupling of arylzinc compounds was achieved by the use of N-chlorosuccinimide (NCS) or O2 as an oxidant. Different reaction pathways were involved in the catalytic reactions depending on the oxidants; NCS or O2 probably oxidized I- or Pd0 to I+ or Pd2+, respectively. This reaction disclosed a new and facile synthetic method of biaryls from aryl halides or arenes via arylzinc intermediates.