3774-52-5

Basic information

• Product Name: 4-HYDROXYPHENYL THIOCYANATE
• Synonyms: 4-HYDROXYPHENYL THIOCYANATE;4-Thiocyanatophenol;4-Thiocyanophenol;p-Thiocyanatophenol;Thiocyanic acid 4-hydroxyphenyl ester
• CAS NO: 3774-52-5
• Molecular Formula: C₇H₅NOS
• Molecular Weight: 151.19
• Mol File: 3774-52-5.mol
• Article Data: 35

Chemical Properties

• Boiling Point: 309.1°C at 760 mmHg
• Flash Point: 140.8°C
• Appearance: /
• Density: 1.35g/cm³
• Vapor Pressure: 0.000358mmHg at 25°C
• Refractive Index: 1.654
• CAS DataBase Reference: 4-HYDROXYPHENYL THIOCYANATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-HYDROXYPHENYL THIOCYANATE(3774-52-5)
• EPA Substance Registry System: 4-HYDROXYPHENYL THIOCYANATE(3774-52-5)

Safety Data

• Hazardous Substances Data: 3774-52-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H5NOS/c8-5-10-7-3-1-6(9)2-4-7/h1-4,9H

Upstream product

• 2987-46-4 4-thiocyanatoaniline 
• 56-23-5 tetrachloromethane 
• 5961-98-8 thiocyanatochloride 
• 108-95-2 phenol 
• 505-14-6 thiocyanogen 
• 333-20-0 potassium thioacyanate 
• 540-72-7 sodium thiocyanide 
• 1147550-11-5 ammonium thiocyanate 
• 28241-61-4 ammonia thiocyanic acid 
• 592-87-0 lead(II) thiocyanate 
• 637-89-8 4-sulfanylphenol 
• 859214-49-6 2-cyano-4-chloro-5-methoxypyridazin-3(2H)-one 
• 859214-48-5 2-cyano-4,5-dichloropyridazin-3(2H)-one 
• 75-52-5 nitromethane 

Downstream Products

• 15015-57-3 bis(4-hydroxyphenyl)disulfide 
• 637-89-8 4-sulfanylphenol 
• 89641-98-5 2-Nitro-4-thiocyanato-phenol 
• 5285-90-5 4-thiocyanatoanisole 
• 6860-75-9 Vinylsulfonsaeure-(4-thiocyanato-phenylester) 
• 83038-52-2 p-thiocyanatophenyl p'-decylbenzoate 
• 83038-50-0 p-thiocyanatophenyl p'-nonyloxybenzoate 
• 83038-48-6 p-thiocyanatophenyl p'-propyloxybenzoate 
• 83038-49-7 p-thiocyanatophenyl p'-pentyloxybenzoate 
• 404389-74-8 4-octyloxyphenyl thiocyanate 
• 102231-96-9 p-octyloxybenzenethiol 

Relevant articles and documents

N-Thiocyanato-2,10-camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents

The synthesis of bench-stable electrophilic thiocyanating reagents was depicted in two steps from readily available starting materials in good yields. These newly designed electrophilic reagents were successfully applied for the thiocyanation of different

An electrochemical method for deborylative seleno/thiocyanation of arylboronic acids under catalyst- And oxidant-free conditions

An electrochemical deborylative seleno/thiocyanation of arylboronic acids has been well established to synthesize the corresponding aryl seleno/thiocyanates with good functional group tolerance under ambient conditions. A gram-scale reaction has been performed to highlight the advantages of the protocol. Preliminary mechanistic studies indicate that the oxidation of the seleno/thiocyanate anion occurs prior to that of the arylboronic acid substrate in galvanostatic mode, and that free radicals are involved in the process.

Visible-light-enabled regioselective aerobic oxidative C(sp2)-H thiocyanation of aromatic compounds by Eosin-Y photocatalyst

Herein, visible-light-enabled regioselective aerobic oxidative C(sp2)-H thiocyanation of aromatic compounds has been developed by employing eosin-Y as effective photocatalyst and oxygen as the green terminal oxidant. This process featured green, efficient and operationally simple. Furthermore, the practicality and utility of this protocol was demonstrated by the gram scale synthesis. Mechanistic studies suggested that this reaction was realized via a photoredox radical pathway.