378786-44-8Relevant articles and documents
Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams
Chen, Jian-Qiang,Chang, Rui,Lin, Jun-Bing,Luo, Yong-Chun,Xu, Peng-Fei
, p. 2395 - 2398 (2018)
This work develops a photocatalysis method for the synthesis of γ-spirolactams through a tandem intramolecular 1,5-HAT reaction-cyclization process. A variety of novel γ-spirolactams are prepared in good to excellent yields with this method. This transfor
Intramolecular 1,5-H transfer reaction of aryl iodides through visible-light photoredox catalysis: A concise method for the synthesis of natural product scaffolds
Chen, Jian-Qiang,Wei, Yun-Long,Xu, Guo-Qiang,Liang, Yong-Min,Xu, Peng-Fei
supporting information, p. 6455 - 6458 (2016/05/24)
The intramolecular 1,5-H transfer reaction of the aryl radicals generated from unactivated aryl iodides by photocatalysis is described. The features of this transformation are operational simplicity, excellent yields, mild reaction conditions, and good fu
Synthesis, structure, and chemoselective reactivity of N-(2-iodylphenyl) acylamides: Hypervalent iodine reagents bearing a pseudo-six-membered ring.scaffold
Ladziata, Uladzimir,Koposov, Alexey Y.,Lo, Ka Y.,Willging, Jeff,Nemykin, Victor N.,Zhdankin, Viktor V.
, p. 7127 - 7131 (2007/10/03)
A pseudo-benziodoxazine structure with intramolecular secondary I...O bonding, as shown by X-ray analysis, is seen in a series of N-(2-iodylphenyl) acylamides prepared from 2-iodoaniline (see scheme). These compounds contain a six-membered pseudocyclic scaffold about an iodine(v) center and are able to oxidize either alcohols or sulfides, with the reactivity depending largely on the substitution pattern on the amide group adjacent to the iodyl moiety. (Chemical Equation Presented).
