37891-39-7

Basic information

• Product Name: Silane, [bis(phenylthio)methyl]trimethyl-
• CAS NO: 37891-39-7
• Molecular Formula: C16H20S2Si
• Molecular Weight: 304.552
• Mol File: 37891-39-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, [bis(phenylthio)methyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [bis(phenylthio)methyl]trimethyl-(37891-39-7)
• EPA Substance Registry System: Silane, [bis(phenylthio)methyl]trimethyl-(37891-39-7)

Safety Data

• Hazardous Substances Data: 37891-39-7(Hazardous Substances Data)

Upstream product

• 79239-13-7 trimethylsilane 
• 141-05-9 Diethyl maleate 
• 110-83-8 cyclohexene 
• 623-91-6 diethyl Fumarate 
• 100-42-5 styrene 
• 13307-76-1 [bis(phenylthio)methyl]lithium 
• 78-94-4 methyl vinyl ketone 
• 88738-21-0 trimethylsilane 
• 71-43-2 benzene 
• 30536-77-7 <(phenylthio)(trimethylsilyl)methyl>lithium 
• 882-33-7 diphenyldisulfane 
• 5796-98-5 bis-trimethylsilanyl peroxide 
• 3561-67-9 bis(phenylthio)methane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 87729-81-5 1,1-Bis(phenylthio)-1-(trimethylsilyl)ethane 
• 87729-86-0 Bis(phenylthio)bis(trimethylsilyl)methane 
• 87729-84-8 1,1-diphenyl-2-phenylthiohex-1-ene 
• 87729-87-1 (2,2-Diphenyl-1-phenylsulfanyl-vinyl)-trimethyl-silane 
• 87729-83-7 2-phenylthio-1-phenylhex-1-ene 
• 87729-85-9 (1-phenylthiopentylidene)cyclohexane 
• 107014-79-9 5-phenylthiodec-5-ene 
• 86887-88-9 phenyl hex-1-en-2-yl sulfide 
• 59176-57-7 (Z)-1-phenylthio-1-trimethylsilyl-2-phenylethylene 
• 16158-83-1 1-methyl-2-phenylethenyl phenyl sulfide 
• 62762-20-3 1-phenylthio-1-trimethylsilylethene 
• 144765-03-7 C₂₁H₂₃F₃S₂ 
• 144764-97-6 2-Cyclohexyl-3,3,3-trifluoro-thiopropionic acid S-phenyl ester 
• 144764-98-7 3,3,3-Trifluoro-2-phenyl-thiopropionic acid S-phenyl ester 

Relevant articles and documents

Organylthio(silyl)carbenes

The title carbenes 5 can be generated either from diazo compounds 9 by copper-catalyze d catalysis or from chloro(organylthio)methylsilanes 12 by base-induced α-elimination, This is confirmed, by [2+1] cycloadditions with alkenes to give the cyclopropanes

Alkyl- and arylsubstituted ketenedithioacetal tetroxides: Diels-Alder reactivity and reductive desulfonylation of the adducts

The Diels-Alder reactivity of the representative alkyl and aryl-substituted ketenedithioacetal tetroxides of general formula 1 is reported. These dienophiles reacted under thermal conditions (refluxing toluene) with cyclopentadiene to afford predominantly

REACTION OF TRIMETHYLSILANE WITH ARENES AND ALK-1-ENES IN THE PRESENCE OF LEWIS ACID

trimethylsilane reacted with arenes and alk-1-enes in the presence of a Lewis acid to give the Friedel-Crafts product and the ene product, respectively.