38433-24-8Relevant articles and documents
Reactions of Bridged Halosubstituted Adamantane Derivatives with Nitric Acid
Klimochkin,Leonova,Moiseev,Aleksandrov
, p. 340 - 344 (2007/10/03)
Reactions of bridged halosubstituted adamantane derivatives with nitric acid result in nitrolysis products. In the presence of acetic anhydride, the reactions proceed at nodal positions to form nitroxy derivatives, while in the case of 2,2-dichloroadamantane, the formation of a 1,4,4-trichloro-substituted derivative is observed. The nitroxylation of 2-fluoroadamantane results in the formation of predominantly products with the Z-configuration.