38559-92-1

Basic information

• Product Name: 4-BENZYLOXYPHENOXYACETIC ACID
• Synonyms: VITAS-BB TBB000339;4-BENZYLOXYPHENOXYACETIC ACID;LABOTEST-BB LT00454174;[4-(phenylmethoxy)phenoxy]acetic acid;2-[4-(phenylMethoxy)phenoxy]-;2-[4-(PhenylMethoxy)phenoxy]-acetic acid;2-[4-(phenylmethoxy)phenoxy]ethanoic acid;Acetic acid, [4-(phenylmethoxy)phenoxy]-
• CAS NO: 38559-92-1
• Molecular Formula: C₁₅H₁₄O₄
• Molecular Weight: 258.27
• EINECS: 254-000-2
• Product Categories: Phenoxyacetic Acids and Alcohols (substituted);API intermediates
• Mol File: 38559-92-1.mol
• Article Data: 5

Chemical Properties

• Melting Point: 139-140°C
• Boiling Point: 436.9°Cat760mmHg
• Flash Point: 164.9°C
• Appearance: /
• Density: 1.234g/cm³
• Vapor Pressure: 2.1E-08mmHg at 25°C
• Refractive Index: 1.586
• PKA: 3.24±0.10(Predicted)
• BRN: 2469260
• CAS DataBase Reference: 4-BENZYLOXYPHENOXYACETIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BENZYLOXYPHENOXYACETIC ACID(38559-92-1)
• EPA Substance Registry System: 4-BENZYLOXYPHENOXYACETIC ACID(38559-92-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 38559-92-1(Hazardous Substances Data)

Usage

General Description

4-BENZYLOXYPHENOXYACETIC ACID is a chemical compound with the molecular formula C16H14O4. 4-BENZYLOXYPHENOXYACETIC ACID is a derivative of phenoxyacetic acid, containing a benzyl ether functional group. It has been used in various pharmaceutical and agricultural applications, such as a precursor for the synthesis of other organic compounds and as an herbicide. 4-BENZYLOXYPHENOXYACETIC ACID has also been studied for its potential anti-inflammatory and anti-cancer properties, as well as its ability to enhance plant growth and development. Its versatile properties make it an important compound in the fields of chemistry, medicine, and agriculture.

InChI:InChI=1/C15H14O4/c16-15(17)11-19-14-8-6-13(7-9-14)18-10-12-4-2-1-3-5-12/h1-9H,10-11H2,(H,16,17)

Upstream product

• 142717-44-0 Ethyl 2-(4-benzyloxyphenoxy)ethanoate 
• 107-59-5 tert-Butyl chloroacetate 
• 103-16-2 4-Benzyloxyphenol 
• 79-14-1 glycolic Acid 
• 19578-68-8 4-(4-benzyloxyphenyl) iodide 
• 81466-35-5 (4-benzyloxyphenoxy)acetic acid methyl ester 
• 4897-84-1 Methyl 4-bromobutyrate 

Downstream Products

• 1878-84-8 (4-hydroxyphenoxy)acetic acid 
• 142717-45-1 4-Propylphenyl 2-(4-benzyloxyphenoxy)ethanoate 
• 67856-23-9 p-(2-hydroxyethoxy)benzyloxybenzene 
• 90414-55-4 N-cyclohexyl-2-<4-(benzyloxy)phenoxy>acetamide 
• 36983-61-6 5'-O-<<4-(benzyloxy)phenoxy>acetyl>thymidine 
• 206872-00-6 (4-benzyloxyphenyl)oxyacetic acid chloride 
• 142741-91-1 4-Propylphenyl 2-(4-hydroxyphenoxy)ethanoate 
• 3351-59-5 2-(4-benzyloxyphenoxy)ethyl bromide 
• 90414-53-2 5'-O-<2-<4-(benzyloxy)phenoxy>ethyl>thymidine 
• 845744-02-7 ethyl 4-(2-chlorophenyl)-5-cyano-6-methyl-2-[(2-{2-[4-(phenylmethoxy)phenoxy]acetylamino}ethoxy)methyl]-1,4-dihydropyridine-3-carboxylate 
• 20872-28-0 ethyl 2-(4-hydroxyphenoxy)acetate 
• 103-16-2 4-Benzyloxyphenol 
• 1489287-92-4 1-(4-benzyloxyphenoxyacetyl)-4-(4-phenylbenzyl)-thiosemicarbazide 
• 380336-87-8 4-benzyloxyphenoxyacetic acid hydrazide 

Relevant articles and documents

Extractant as well as preparation method and application thereof

The invention relates to the field of separation and enrichment of metals, in particular to an extractant, a preparation method and application thereof. The preparation method comprises the followingsteps that a phenol compound reacts with a halogenated carboxylic acid derivative or halogenated carboxylate in a solvent, then acidifying is carried out, and the phenoxy carboxylic acid extractant issynthesized. The prepared extractant can be used for enriching rare earth in rare earth mineral leachate after being saponified by an alkaline compound; compared with the existing extractant, the extractant has the advantages of being higher in precipitation capacity, high in precipitation efficiency and large in precipitation particles, facilitating the separation of a rare earth extraction complex and a water phase and improving the production efficiency; and moreover, the extractant can further be used for selectively recovering/separating valuable metals from different industries.

Copper(II)-catalyzed hydroxylation of aryl halides using glycolic acid as a ligand

Copper(II)-catalyzed hydroxylation of aryl halides has been developed to afford functionalized phenols. The protocol utilizes the reagent combination of Cu(OH)2, glycolic acid, and NaOH in aqueous DMSO, all of which are cheap, readily available, and easily removable after the reaction. A broad range of aryl iodides and activated aryl bromides were transformed into the corresponding phenols in excellent yields. Moreover, it has been shown that C-O(alkyl)-coupled product, instead of phenol, can be predominantly formed under similar reaction conditions.

The Synthesis and Transition Temperatures of Novel Low Molar Mass Cholesteric Materials Derived from (R)-2-(4-Hydroxyphenoxy)propanoic Acid

A comprehensive series of (R)-2-(4-substituted-phenoxy)propanoates and (R)-2-(4-substituted-phenoxy)propanonitriles have been prepared.A wide variety of 4-substituents and ester functions have been examined to determine how the position of the chiral centre affects the cholesteric phase formation in these classes of materials; the synthesis of these novel materials, their transition temperatures and a procedure for assessing their optical purity are described and discussed.Mesogenicity is significantly depressed if the chiral centre is placed centrally within the molecule.