39192-94-4

Basic information

• Product Name: 4-methoxy-N-(4-methylphenyl)benzamide
• Synonyms: 4-Methoxy-N-(4-methylphenyl)benzamide; benzamide, 4-methoxy-N-(4-methylphenyl)-
• CAS NO: 39192-94-4
• Molecular Formula: C₁₅H₁₅NO₂
• Molecular Weight: 241.2851
• Mol File: 39192-94-4.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 318.2°C at 760 mmHg
• Flash Point: 146.2°C
• Density: 1.156g/cm³
• Vapor Pressure: 0.000367mmHg at 25°C
• Refractive Index: 1.61
• CAS DataBase Reference: 4-methoxy-N-(4-methylphenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-N-(4-methylphenyl)benzamide(39192-94-4)
• EPA Substance Registry System: 4-methoxy-N-(4-methylphenyl)benzamide(39192-94-4)

Safety Data

• Hazardous Substances Data: 39192-94-4(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 100-07-2 4-methoxy-benzoyl chloride 
• 58618-94-3 benzoic p-methoxybenzoic anhydride 
• 52764-31-5 α-(p-methoxyphenyl)-N-(p-tolyl)nitrone 
• 356771-88-5 4-methoxybenzoyl N-phenylcarbamoyl selenide 
• 105223-29-8 4-methoxybenzenecarboselenoic acid 
• 300382-54-1 (4-methoxy-phenyl)-p-tolyl-methanone oxime 
• 123-11-5 4-methoxy-benzaldehyde 
• 726-42-1 di-p-tolylcarbodiimide 
• 121-97-1 4-Methoxypropiophenone 
• 622-58-2 p-Tolylisocyanate 
• 100-09-4 4-methoxybenzoic acid 
• 624-31-7 4-tolyl iodide 
• 2393-23-9 4-methoxy-benzylamine 

Downstream Products

• 111270-65-6 N-(2-bromo-4-methyl phenyl)-4-methoxybenzamide 
• 110274-41-4 3-bromo-4-methoxy-benzoic acid-(2,5-dibromo-4-methyl-anilide) 
• 97317-28-7 4-methoxy-N-(p-tolyl)benzothioamide 
• 1017572-79-0 (Z)-N-(1-(4-methoxyphenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methylaniline 
• 1340595-27-8 N-[(E)-1,4-diphenylbut-1-en-3-ynyl]-4-methoxy-N-(4-methylbenzyl)-benzamide 
• 1340595-28-9 C₃₃H₂₉NO₂ 
• 1340595-29-0 C₃₉H₄₁NO₂ 
• 3424-93-9 4-methoxyphenylacetamide 
• 62613-67-6 5-methyl-2-(4-methoxyphenyl)-1H-indole 

Relevant articles and documents

Iron-catalyzed cross-coupling of N?methoxy amides and arylboronic acids for the synthesis of N-aryl amides

An efficient iron-catalyzed synthesis of N-aryl amides from N?methoxy amides and arylboronic acids is developed. FeCl3 is used as the sole catalyst for the cross-coupling reaction between N?methoxy amides and arylboronic acids without any other

α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles

Imidoyl sulfoxonium ylides are presented for the first time as potential precursors to generate α-imino metal-carbene intermediates and applied in direct C-H functionalization reactions catalyzed by [Ir(cod)Cl]2 (4 mol %) to provide 2-substituted indoles (up to 70% yield) in just one step. This class of sulfur ylide is successfully obtained from imidoyl chloride and dimethylsulfoxonium methylide (23 new examples in 45-85% yield) or by imino group formation from the corresponding β-keto sulfoxonium ylides and anilines in the presence of TiCl4 as a Lewis acid (9 examples in 33-94% yield).

The use of Cr (CO)6 as an alternative CO source in Pd-catalyzed C-N bond formation: Synthesis of benzamides

An efficient strategy for the synthesis of benzamides from acetamides and aryl iodides using 1?mol% Pd (OAc)2 as catalyst and Cr (CO)6 as CO-precursor is described. This new synthetic methodology displays high functional group tolerance on both substrates and avoids the need for ligands, reducing agents, or other additives. The corresponding products were obtained in good to excellent yields at atmospheric pressure under mild reaction conditions.