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39520-63-3

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39520-63-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 39520-63-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,9,5,2 and 0 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 39520-63:
(7*3)+(6*9)+(5*5)+(4*2)+(3*0)+(2*6)+(1*3)=123
123 % 10 = 3
So 39520-63-3 is a valid CAS Registry Number.

39520-63-3Relevant articles and documents

Stereoselective Carbocyclization of Vinyloxiranes Catalyzed by Lewis Acids: Construction of the Musellarin Tricyclic Core

Yang, Sehui,Park, Euijin,Kim, Jimin

supporting information, p. 667 - 670 (2021/02/05)

Stereoselective carbocyclizations of vinyloxiranes were efficiently catalyzed by Lewis acids to provide cyclic homoallyl alcohols as single isomers. The choice of Lewis acid, B(C6F5)3 was crucial for the stereoselective tr

Cascade reaction including a formal [5?+?2] cycloaddition by use of alkyne-Co2(CO)6 complex

Sakata, Yuki,Yasui, Eiko,Mizukami, Megumi,Nagumo, Shinji

supporting information, p. 755 - 759 (2019/02/20)

A new cascade reaction including formal [5 + 2] cycloaddition was developed. Treatment of homocinnamyl alcohol and Co2(CO)6-complexed arylpropynal with BF3·OEt2 resulted in the generation of hydrobenzocyclohepta

Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation

Wu, Xuesong,Cruz, Faben A.,Lu, Alexander,Dong, Vy M.

, p. 10126 - 10130 (2018/08/23)

We report a Rh-catalyst for accessing olefins from primary alcohols by a C-C bond cleavage that results in dehomologation. This functional group interconversion proceeds by an oxidation-dehydroformylation enabled by N,N-dimethylacrylamide as a sacrificial acceptor of hydrogen gas. Alcohols with diverse functionality and structure undergo oxidative dehydroxymethylation to access the corresponding olefins. Our catalyst protocol enables a two-step semisynthesis of (+)-yohimbenone and dehomologation of feedstock olefins.

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