39627-97-9Relevant articles and documents
Synthesis of a bulky bis(imino)pyridine compound: A methodology for systematic variation of steric bulk and energetic implications for metalation
Steves, Janelle E.,Kennedy, Margaret D.,Chiang, Karen P.,Kassel, William S.,Dougherty, William G.,Dudley, Timothy J.,Zubris, Deanna L.
, p. 1214 - 1222 (2009)
A new bis(imino)pyridine compound, 2,6-{(2,6-Me2-C 6H3)NC(t-Bu)}2C5H3N (6), has been synthesized with t-butyl substituents on the imino carbon atoms. The stepwise synthetic method for assem
Triketiminate bis(borohydride) complexes of rare-earth metals [(2,6-Me2C6H3N=CMe)2C(2,6-Me2C6H3N=CBut)]Ln(BH4)2(THF)2 (Ln = Y, Nd): sy
Skvortsov,Cherkasov,Trifonov
, p. 1665 - 1674 (2018/01/01)
A new triketimine (2,6-Me2C6H3N=CMe)2CH(2,6-Me2C6H3N=CBut) (1) was synthesized by the reaction of imidoyl chloride 2,6-Me2C6H3N=CClBu
Sulphuric acid immobilized on silica gel (H2SO4-SiO2) as an eco-friendly catalyst for transamidation
Rasheed,Rao, D. Nageswar,Reddy, A. Siva,Shankar, Ravi,Das, Parthasarathi
, p. 10567 - 10574 (2015/02/05)
A novel method of transamidation of carboxamides with amines by using catalytic amounts of H2SO4-SiO2 has been developed under solvent free conditions. The transamidation is compatible with a wide range of aromatic, heteroaromatic, aliphatic, cyclic/acyclic primary or secondary amines. The metal/solvent-free conditions represent a significant improvement over other existing methods as the reaction can be performed in open air conditions and no column purification is required. The versatility of this methodology was further demonstrated by synthesizing the commercially available drug procainamide.