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401-44-5

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401-44-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 401-44-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,0 and 1 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 401-44:
(5*4)+(4*0)+(3*1)+(2*4)+(1*4)=35
35 % 10 = 5
So 401-44-5 is a valid CAS Registry Number.

401-44-5Relevant articles and documents

A laser flash photolysis and quantum chemical study of the fluorinated derivatives of singlet phenylnitrene

Gritsan,Gudmundsdottir,Tigelaar,Zhu,Karney,Hadad,Platz

, p. 1951 - 1962 (2001)

Laser flash photolysis (LFP, Nd:YAG laser, 35 ps, 266 nm, 10 mJ or KrF excimer laser, 10 ns, 249 nm, 50 mJ) of 2-fluoro, 4-fluoro, 3,5-difluoro, 2,6-difluoro, and 2,3,4,5,6-pentafluorophenyl azides produces the corresponding singlet nitrenes. The singlet

Chemoselective electrochemical reduction of nitroarenes with gaseous ammonia

Chang, Liu,Li, Jin,Wu, Na,Cheng, Xu

supporting information, p. 2468 - 2472 (2021/04/02)

Valuable aromatic nitrogen compounds can be synthesized by reduction of nitroarenes. Herein, we report electrochemical reduction of nitroarenes by a protocol that uses inert graphite felt as electrodes and ammonia as a reductant. Depending on the cell voltage and the solvent, the protocol can be used to obtain aromatic azoxy, azo, and hydrazo compounds, as well as aniline derivatives with high chemoselectivities. The protocol can be readily scaled up to >10 g with no decrease in yield, demonstrating its potential synthetic utility. A stepwise cathodic reduction pathway was proposed to account for the generations of products in turn.

Visible-light-promoted oxidative dehydrogenation of hydrazobenzenes and transfer hydrogenation of azobenzenes

Wang, Xianya,Wang, Xianjin,Xia, Chungu,Wu, Lipeng

supporting information, p. 4189 - 4193 (2019/08/07)

Azo compounds are widely used in the pharmaceutical and chemical industries. Here, we report the use of a non-metal photo-redox catalyst, Eosin Y, to synthesize azo compounds from hydrazine derivatives. The use of visible-light with air as the oxidant makes this process sustainable and practical. Moreover, the visible-light-driven, photo-redox-catalyzed transfer hydrogenation of azobenzenes is compatible with a series of hydrogen donors such as phenyl hydrazine and cyclic amines. Compared with traditional (thermal/transition-metal) methods, our process avoids the issue of over-reduction to aniline, which extends the applicability of photo-redox catalysis and confirms it as a useful tool for synthetic organic chemistry.

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