40299-78-3

Basic information

• Product Name: pentacyano(pyrazine)ferrate(II)^(3-)
• Synonyms: pentacyano(pyrazine)ferrate(II)^(3-)
• CAS NO: 40299-78-3
• Molecular Weight: 266.025
• Mol File: 40299-78-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pentacyano(pyrazine)ferrate(II)^(3-)(CAS DataBase Reference)
• NIST Chemistry Reference: pentacyano(pyrazine)ferrate(II)^(3-)(40299-78-3)
• EPA Substance Registry System: pentacyano(pyrazine)ferrate(II)^(3-)(40299-78-3)

Safety Data

• Hazardous Substances Data: 40299-78-3(Hazardous Substances Data)

Upstream product

• 147-84-2 Diethyldithiocarbamic acid 

Relevant articles and documents

The Oxidation of Dithiocarbamate Anion by Substitution Inert Metal Complexes

The kinetics of oxidation of dithiocarbamate anions to thiuram disulfides in aqueous acetone by 3- and 11 other substitution inert metal complexes have been investigated.Outer-sphere electron transfer, resulting in the formation of dithiocarbamate thio radicals, is the rate determining step.A Marcus cross reaction treatment allows an estimate for the redox potential for the dithiocarbamate radical/anion couple.For diethyldithiocarbamate, Edeg(edtc./edtc-) = 425+/-33 mV ν.s.c.e. and the outer-sphere electron self-exchange rate constant is logkex = 7.0+/-0.3.A comparison with thiophenolate oxidation is also given.