4124-81-6Relevant articles and documents
Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol Ethers to Synthesize Functionalized Aryl Alkyl Ketones
Kong, Weiguang,Yu, Changjiang,An, Hejun,Song, Qiuling
, p. 349 - 352 (2018/01/28)
Photoredox-catalyzed decarboxylative alkylation of silyl enol ethers has been developed. Diverse functionalized aryl alkyl ketones were afforded in modest to good yields using N-(acyloxy)phthalimide as an easy access alkyl radical source under mild and operationally simple conditions. The excellent performance of drug molecules such as fenbufen and indomethacin and naturally occurring carboxylic acids such as stearic acid and dehydrocholic acid further demonstrated the practicability of the reaction.
Photoreactions of Benzonitrile with Cyclic Enol Ethers
Mattay, Jochen,Runsink, Jan,Heckendorn, Roland,Winkler, Tammo
, p. 5781 - 5790 (2007/10/02)
Upon irradiation cyclic enol ethers such as 1-methoxy-cyclopentene (4) mainly add across the cyano group of benzonitrile (1) under formation of 2-azabutadienes of an imidoester type.This is in agreement with the so-called ΔG-correlation which was reported