415918-91-1

Basic information

• Product Name: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
• Synonyms: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT;(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS);(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
• CAS NO: 415918-91-1
• Molecular Formula: C₃₆H₃₀NO₂P
• Molecular Weight: 624.54
• Product Categories: Chiral Phosphine;CPN
• Mol File: 415918-91-1.mol
• Article Data: 0

Chemical Properties

• Melting Point: 102-103 °C
• Boiling Point: 710.7 °C at 760 mmHg
• Flash Point: 383.6 °C
• Appearance: white/Powder
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: -0.57±0.20(Predicted)
• Sensitive: moisture sensitive
• CAS DataBase Reference: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT(415918-91-1)
• EPA Substance Registry System: (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT(415918-91-1)

Safety Data

• Hazard Codes: Xn
• Statements: 36/37/38-22
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• Hazardous Substances Data: 415918-91-1(Hazardous Substances Data)

Usage

Description

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT is an organic compound with a complex chemical structure. It is characterized by its unique arrangement of atoms and functional groups, which contribute to its specific properties and potential applications.

Uses

Used in Chemical Synthesis:
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT is used as an organic catalyst for the stereoselective preparation of homoallylic nitriles. Its unique structure allows it to facilitate specific chemical reactions, leading to the formation of desired products with high selectivity and efficiency.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT may be utilized as a key intermediate or building block in the synthesis of various pharmaceutical compounds. Its unique properties and reactivity can contribute to the development of new drugs with improved therapeutic profiles.
Used in Research and Development:
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT can also be employed in research and development settings, where its unique chemical properties can be explored for potential applications in various fields, such as materials science, catalysis, and environmental chemistry.

Reactions

A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins. Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral allylic esters. Asymmetric hydrogenation. Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles. Asymmetric hydrovinylation. Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation. Palladium-catalyzed enantioselective diamination of alkyl dienes.

Downstream Products

• 25150-61-2 pyrrolidine hydrochloride