42295-70-5

Basic information

• Product Name: Methyl-phenyl-thiophosphinsaeure-O-methylester
• Synonyms: Methyl-phenyl-thiophosphinsaeure-O-methylester
• CAS NO: 42295-70-5
• Molecular Weight: 186.214
• Mol File: 42295-70-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Methyl-phenyl-thiophosphinsaeure-O-methylester(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-phenyl-thiophosphinsaeure-O-methylester(42295-70-5)
• EPA Substance Registry System: Methyl-phenyl-thiophosphinsaeure-O-methylester(42295-70-5)

Safety Data

• Hazardous Substances Data: 42295-70-5(Hazardous Substances Data)

Upstream product

• 94235-66-2 Methylphenylphosphinsaeuremethylester 
• 38605-11-7 (+)R-S-methyl methylphenylphosphinothiolate 
• 95202-93-0 4,8-Dimethyl-2-oxo-1,2-diphenyl-2λ⁵-phospha-bicyclo[2.2.2]octa-5,7-diene-5,6-dicarboxylic acid dimethyl ester 
• 90219-11-7 1,2-diphenyl-4,5-dimethyl-1-hydrophosphorin oxide 
• 109891-12-5 3-methyl-4-chloro-1,2-dihydro-1-phenylphosphorin 1-oxide 
• 67-56-1 methanol 
• 3296-60-4 phenylbis(hydroxymethyl)phosphine sulfide 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 
• 13639-62-8 chloromethylphenylphosphine sulfide 
• 122-08-7 benzyltrismethylammonium methoxide 
• 95202-94-1 7-phosphabicyclo<2.2.2>octa-2,5-diene P-sulphide 

Downstream Products

• 6389-79-3 methyl methylphenylphosphinate 
• 42295-73-8 S-methyl methylphenylphosphinothiolate 

Relevant articles and documents

REACTION OF BIS(HYDROXYMETHYL)PHENYLPHOSPHINE SULFIDE AND BIS(HYDROXYMETHYL)PHENYLPHOSPHINE SELENIDE WITH THE DIMETHYLACETAL OF DIMETHYLFORMAMIDE

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Novel 2-Phosphabicyclo[2.2.2]oct-5-ene Derivatives and Their Use in Phosphinylations

The [4 + 2] cycloaddition of the double-bond isomers (A and B) of dihydrophosphinine oxide 1 afforded novel phosphabicyclo[2.2.2]oct-5-ene derivates (2-4), formation of which was justified by PM3 semiempirical calculations. The compounds of dimer type (2-

Generation and Trapping of a C-Unsubstituted Methylenephosphine Sulphide

The synthesis of a 7-phosphabicycloocta-2,5-diene P-sulphide is described; on thermolysis in boiling toluene, this compound generates Ph-P(S)=CH2 which can be trapped by methanol, 2,3-dimethylbutadiene, and benzylideneacetophenone.