42478-41-1Relevant articles and documents
Engineering regioselectivity in the hydrosilylation of alkynes using heterobimetallic dual-functional hybrid catalysts
Downes, James E.,Gautam, Shreedhar,Gon?ales, Vinicius R.,Gooding, J. Justin,Keaveney, Sinead T.,Lian, Jiaxin,Messerle, Barbara A.,Roemer, Max
, p. 226 - 236 (2022/01/19)
The synthesis and characterization of carbon black supported rhodium and iridium heterobimetallic catalysts, termed hybrid catalysts, and their application in the hydrosilylation of alkynes is described. An aryl diazonium grafting procedure was applied to
Synthesis and structure of thienyl Fischer carbene complexes of PtIIfor application in alkyne hydrosilylation
Lamprecht, Zandria,Malan, Frederick P.,Lotz, Simon,Bezuidenhout, Daniela I.
, p. 6220 - 6230 (2021/04/16)
Transmetallation of group 6 thienylene Fischer carbene complexes to PtIIprecursors yielded new examples of neutral platinum(ii) bisethoxycarbene complexes with either 2-thienyl (T) or 5-thieno[2,3-b]thienylene (TT) carbene substituents. The use
Carbon supported hybrid catalysts for controlled product selectivity in the hydrosilylation of alkynes
Roemer, Max,Gon?ales, Vinicius R.,Keaveney, Sinead T.,Pernik, Indrek,Lian, Jiaxin,Downes, James,Gooding, J. Justin,Messerle, Barbara A.
, p. 1888 - 1898 (2021/03/26)
A series of Rh- and Ir-hybrid catalysts with varying tether lengths has been prepared by immobilization of RhI, RhIIIand IrIIIcomplexes on carbon blackviaradical grafting. The performance of the different catalysts was ass