425-38-7Relevant articles and documents
THERMOGRAPHIC INVESTIGATION OF THE DECARBOXYLATION OF SALTS OF PERFLUORINATED CARBOXYLIC ACIDS
Gubanov, V. A.,Zevakin, I. A.,Gurari, V. E.,Tumanova, A. V.,Dolgopol'skii, I. M.,et al.
, p. 1409 - 1412 (2007/10/02)
The thermal stability of the salts of metals of the first group with perfluorinated carboxylic acids was investigated by a differential thermal method.The calculations of the A, E, and n parameters were made on a Minsk 32 computer.For the investigated series of salts the reactions has first-order kinetics.In the case of the pyrolysis of the salts of perfluoromethoxypropionic acid the yield of perfluoromethyl vinyl ether depends not only on the cation of the salt but is determined to a significant degree by the structural features of the carbon skeleton.Tetrafluoroethylene and perfluoromethoxypropionyl fluoride were detected as side products.A mechanism for the process, which explains the formation of the main reaction products, was proposed and confirmed experimentally.