42742-79-0

Basic information

• Product Name: dihydro-β-damascol
• Synonyms: dihydro-β-damascol
• CAS NO: 42742-79-0
• Molecular Weight: 196.333
• Mol File: 42742-79-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dihydro-β-damascol(CAS DataBase Reference)
• NIST Chemistry Reference: dihydro-β-damascol(42742-79-0)
• EPA Substance Registry System: dihydro-β-damascol(42742-79-0)

Safety Data

• Hazardous Substances Data: 42742-79-0(Hazardous Substances Data)

Upstream product

• 28897-21-4 1-(2,2,6-trimethylcyclohex-1-ene-yl)but-3-en-1-ol 
• 23726-91-2 beta damascone 
• 28384-26-1 1-(2,6,6-trimethylcyclohex-1-en-1-yl)butan-1-one 

Downstream Products

• 54345-66-3 Acetic acid 1-(2,6,6-trimethyl-cyclohex-1-enyloxy)-butyl ester 

Relevant articles and documents

Synthesis of β-damascone derivatives with a lactone ring and their feeding deterrent activity against aphids and lesser mealworms

Starting from β-damascone, six new lactones were obtained. The Claisen-Johnson rearrangement of allylic alcohol and halolactonization of γ,δ-unsaturated acid were the key steps of the presented synthesis. The structures of the new derivatives were determined by spectroscopic data. The antifeedant activity of β-damascone towards two insect species with different feeding habits and food preferences, i.e., the peach-potato aphid Myzus persicae (Sulz.) and lesser mealworm, Alphitobius diaperinus Panzer, was studied, as well as the biological consequences of structural modification of the starting substrate. The successive structural modifications of β-damascone that resulted in the greatest antifeedant activity towards M. persicae were the incorporation of a lactone moiety and concomitant presence of bromine in the side chain. All β-damascone derivatives with a lactone moiety deterred the feeding of adults and larvae of A. diaperinus. Halo-δ-lactones were more active than halo-γ-lactones, and A. diaperinus adults were more sensitive to the compounds studied than larvae.