42843-19-6

Basic information

• Product Name: 2-Butanone, 3-hydroxy-3-phenyl-, (S)-
• CAS NO: 42843-19-6
• Molecular Formula: C10H12O2
• Molecular Weight: 164.204
• Mol File: 42843-19-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3-hydroxy-3-phenyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3-hydroxy-3-phenyl-, (S)-(42843-19-6)
• EPA Substance Registry System: 2-Butanone, 3-hydroxy-3-phenyl-, (S)-(42843-19-6)

Safety Data

• Hazardous Substances Data: 42843-19-6(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 78805-22-8 (S)--2-(methoxymethyl)pyrrolidine 
• 22433-39-2 1-methyl-1-phenylallene 
• 127-66-2 2-Phenyl-3-butyn-2-ol 
• 98-86-2 acetophenone 

Relevant articles and documents

Asymmetric dihydroxylation of disubstituted allenes

Asymmetric dihydroxylation of 1,1-disubstituted and 1,3-disubstituted allenes can be used to synthesize chiral α-hydroxy ketones. We have also obtained α,α′-dihydroxy ketones with high enantioselectivity from 1,3-disubstituted allenes. Low conversion of the dihydroxylation of chiral allenes can be used as a kinetic resolution of sterically hindered allenes.

Stereocontrolled Addition Reaction of Organometallics to Chiral α-Keto Amides

Complementary stereoselection in the addition reaction of several organometallics to chiral benzoylformamide, prepared from benzoylformic acid and (S)-2-(methoxymethyl)pyrrolidine, could be achieved using magnesium- and titanium-based reagents to give different diastereomers of atrolactamide.On the other hand, the reaction of phenyl metallics to the corresponding pyruvamide afforded (S)-atrolactamide.