428509-97-1

Basic information

• Product Name: 3',5'-di-O-acetyl-2'-deoxy-5-(p-tolylethynyl)uridine
• Synonyms: 3',5'-di-O-acetyl-2'-deoxy-5-(p-tolylethynyl)uridine
• CAS NO: 428509-97-1
• Molecular Weight: 426.426
• Mol File: 428509-97-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3',5'-di-O-acetyl-2'-deoxy-5-(p-tolylethynyl)uridine(CAS DataBase Reference)
• NIST Chemistry Reference: 3',5'-di-O-acetyl-2'-deoxy-5-(p-tolylethynyl)uridine(428509-97-1)
• EPA Substance Registry System: 3',5'-di-O-acetyl-2'-deoxy-5-(p-tolylethynyl)uridine(428509-97-1)

Safety Data

• Hazardous Substances Data: 428509-97-1(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 376367-55-4 5-((4-methylphenyl)ethynyl)-2'-deoxyuridine 
• 54-42-2 5-Iodo-2'-deoxyuridine 
• 1956-30-5 3',5'-O-diacetyl-5-iodo-2'-deoxyuridine 
• 766-97-2 4-n-methylphenylacetylene 

Downstream Products

• 847659-70-5 3',5'-di-O-acetyl-3-(2'-deoxy-β-D-ribofuranosyl)-6-(4-methylphenyl)-2,3-dihydrofuro[2,3-d]pyrimidin-2-one 
• 1055900-96-3 C₂₂H₂₁ClN₂O₇ 

Relevant articles and documents

Synthesis of dicobalt hexacarbonyl 5-p-tolylethynyl-2′-deoxyuridine

Reactions of 5-p-tolylethynyl-2′-deoxyuridine and 3′,5′-diO-acetyl-5-p-tolylethynyl-2′-deoxyuridine with Co2(CO)8 in THF gave 5-p-tolC2[Co2(CO)6]-2′-deoxyuridine and 3′,5′-diO-acetyl-5-p-tolC2[Co2(CO) 6]-2′-deoxyuridine (92 and 66%).

Zinc-catalyzed cycloisomerizations. Synthesis of substituted furans and furopyrimidine nucleosides

(Chemical Equation Presented) 5-Endo-dig cycloisomerization of 1,4- and 1,2,4- mostly aryl-substituted but-3-yn-1-ones in the presence of a catalytic amount of zinc chloride etherate (10 mol %) in dichloromethane at room temperature gave 2,5-di- and 2,3,5