4289-97-8

Basic information

• Product Name: FOR-VAL-OH
• Synonyms: N-FORMYL-VALINE;N-FORMYL-L-VALINE;FOR-VALINE;FOR-VAL-OH;FORMYL-L-VALINE;N-FORMYL-L-VALINE 98+%;(S)-2-(Formylamino)-3-methylbutanoic acid;(S)-2-(Formylamino)-3-methylbutyric acid
• CAS NO: 4289-97-8
• Molecular Formula: C₆H₁₁NO₃
• Molecular Weight: 145.16
• EINECS: 224-291-0
• Product Categories: Valine [Val, V]
• Mol File: 4289-97-8.mol
• Article Data: 19

Chemical Properties

• Melting Point: 153 °C
• Boiling Point: 355.7 °C at 760 mmHg
• Flash Point: 168.9 °C
• Appearance: /
• Density: 1.124 g/cm³
• Vapor Pressure: 5.12E-06mmHg at 25°C
• Refractive Index: 12 ° (C=4, EtOH)
• Storage Temp.: Store at RT.
• PKA: 3.51±0.10(Predicted)
• CAS DataBase Reference: FOR-VAL-OH(CAS DataBase Reference)
• NIST Chemistry Reference: FOR-VAL-OH(4289-97-8)
• EPA Substance Registry System: FOR-VAL-OH(4289-97-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 24/25-26
• Hazardous Substances Data: 4289-97-8(Hazardous Substances Data)

Usage

Chemical Properties

White to off-white powder

Uses

Intermediate of gramicidin A biosynthesis.

InChI:InChI=1/C6H11NO3/c1-4(2)5(6(9)10)7-3-8/h3-5H,1-2H3,(H,7,8)(H,9,10)/t5-/m0/s1

Upstream product

• 64-18-6 formic acid 
• 516-06-3 D,L-valine 
• 93033-04-6 N-[1-(Benzoimidazole-1-carbonyl)-2-methyl-propyl]-formamide 
• 2258-42-6 formyl acetic anhydride 
• 72-18-4 L-valine 
• 109-94-4 formic acid ethyl ester 
• 75-44-5 phosgene 
• 94899-85-1 valinotricin 
• 113388-44-6 (formyloxy)(acetoxy)phenylmethane 

Downstream Products

• 640-68-6 D-Val-OH 
• 72-18-4 L-valine 
• 104743-88-6 N-formyl-DL-valine anilide 
• 78581-05-2 For-Val-Phe-OMe 
• 101496-73-5 N-(N-formyl-valyl)-phenylalanine ; optically inactive substance 
• 97100-97-5 N-(N-formyl-valyl)-phenylalanine methyl ester; optically inactive substance 
• 94664-20-7 3-Formyl-4-isopropyl-5-oxazolidinone 
• 94899-85-1 valinotricin 
• 113276-96-3 valilactone 
• 78342-42-4 (S)-2-isopropyl-3,6-dimethoxy-2,5-dihydropyrazine 
• 87900-19-4 (2R,5S)-2-Benzyl-5-isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazine 
• 78354-69-5 (2S,5R)-2-Isopropyl-3,6-dimethoxy-5-((E)-3-phenyl-allyl)-2,5-dihydro-pyrazine 
• 78342-45-7 (2S,5R)-2,5-dihydro-3,6-dimethoxy-2-isopropyl-5-(3-phenyl-2-propyn-1-yl)pyrazine 
• 78342-44-6 (2R,5S)-2-(3,4-Dimethoxy-benzyl)-5-isopropyl-3,6-dimethoxy-2,5-dihydro-pyrazine 

Relevant articles and documents

Effector enhanced enantioselective hydroformylation

In this communication, we report rhodium DIMPhos complexes with an integrated DIM-receptor that can bind carboxylate containing effectors and their application in the rhodium catalyzed hydroformylation reaction. The binding of chiral effectors in non-chiral [Rh(DIMPhos)] catalysts does not lead to enantioselective hydroformylation, but the binding of either achiral or chiral effectors can significantly enhance the enantioselectivity induced by the chiral Rh-metal complexes. For example, the supramolecular complex [Rh]/[1S?L3] displays high regio- and enantioselectivity in the hydroformylation of vinyl acetate (72% ee, and b/l >99), whereas in absence of this effector the ee is around 17%.

Formyloxyacetoxyphenylmethane as an N-Formylating Reagent for Amines, Amino Acids, and Peptides

Formyloxyacetoxyphenylmethane is a stable, water-tolerant, N-formylating reagent for primary and secondary amines that can be used under solvent-free conditions at room temperature to prepare a range of N-formamides, N-formylanilines, N-formyl-α-amino acids, N-formylpeptides, and an isocyanide.

ANTIFOULING AGENT FOR UNDERWATER ADHERING ORGANISMS HAVING AMINO ACID ISONITRILE SKELETON

PROBLEM TO BE SOLVED: To provide a novel antifouling agent for underwater adhering organisms having excellent characteristics compared with well-known antifouling agents. SOLUTION: An antifouling agent for underwater adhering organisms comprises a compound represented by formula (I) or salt thereof, or solvate thereof, as an active ingredient. COPYRIGHT: (C)2015,JPO&INPIT