4316-58-9

Basic information

• Product Name: Tris(4-bromophenyl)amine
• Synonyms: TRIS(4-BROMOPHENYL)AMINE;TRIS(4-BROMOPHENYL)AMIN;4,4',4"-Tribromotriphenylamine;TRI(4-BROMOPHENYL)AMINE;4,4',4''-Nitrilotris(1-bromobenzene);N,N-Bis(4-bromophenyl)-4-bromoaniline;4-bromo-N,N-bis(4-bromophenyl)aniline;4-broManyl-N,N-bis(4-broMophenyl)aniline
• CAS NO: 4316-58-9
• Molecular Formula: C₁₈H₁₂Br₃N
• Molecular Weight: 482.01
• EINECS: 1592732-453-0
• Product Categories: Electronic Chemicals;Acid Anhydrides, etc. (Reagents for Conducting Polymer Research);Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Reagents for Conducting Polymer Research;White to light yellow crystalline powder;White powder;Amines;C11 to C38;Nitrogen Compounds
• Mol File: 4316-58-9.mol
• Article Data: 69

Chemical Properties

• Melting Point: 141-143 °C(lit.)
• Boiling Point: 514.9 °C at 760 mmHg
• Flash Point: 100°C
• Appearance: pale green powder
• Density: 1.79 g/cm³
• Vapor Pressure: 1.03E-10mmHg at 25°C
• Refractive Index: 1.692
• Storage Temp.: Refrigerator
• Solubility: Soluble in toluene.
• PKA: -4.91±0.50(Predicted)
• Stability: Stable. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: Tris(4-bromophenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: Tris(4-bromophenyl)amine(4316-58-9)
• EPA Substance Registry System: Tris(4-bromophenyl)amine(4316-58-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 4316-58-9(Hazardous Substances Data)

Usage

Description

Tris(4-bromophenyl)amine is an organic compound characterized by its pale green powder form. It is composed of three 4-bromophenyl groups attached to an amine core, which contributes to its unique chemical properties and potential applications in various fields.

Uses

Used in Chemical Synthesis:
Tris(4-bromophenyl)amine is used as a key intermediate in the synthesis of porous luminescent covalent-organic polymers (COPs). Its unique structure and chemical properties make it a valuable component in the development of advanced materials with potential applications in various industries.
Used in Material Science:
In the Material Science industry, Tris(4-bromophenyl)amine is used as a building block for the creation of novel materials with specific properties. Its incorporation into COPs can lead to the development of materials with enhanced luminescence, which can be utilized in various applications such as sensors, optoelectronics, and other advanced technologies.
Used in Pharmaceutical Research:
Due to its unique chemical structure, Tris(4-bromophenyl)amine may also find applications in the pharmaceutical industry as a starting material for the development of new drugs or drug candidates. Its potential interactions with biological targets can be explored for the treatment of various diseases and conditions.

InChI:InChI=1/C18H12Br3N/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

Upstream product

• 603-34-9 N,N-diphenylaminobenzene 
• 3310-62-1 2,3-diazabicyclo[2.2.2]oct-2-ene 
• 78065-12-0 tris(4-bromophenyl)ammoniumyl hexafluoroantimonate 
• 3282-32-4 2-diazo-acetophenone 
• 71-50-1 acetate 
• 10442-39-4 tetra-n-butylammonium cyanide 
• 10534-59-5 tetrabutylammonium acetate 
• 83026-08-8 Caprinsaeure-4-methoxybenzylester 
• 83026-07-7 Decanoic acid 2,4-dimethoxy-benzyl ester 
• 108-88-3 toluene 
• 589-87-7 1,4-bromoiodobenzene 
• 106-40-1 4-bromo-aniline 
• 34283-63-1 tetrabutylammonium pelargonate 
• 51012-12-5 Tetrabutylammonium hydrogen diacetate 

Downstream Products

• 135761-35-2 tris<4-trimethylsilyl)phenyl>amine 
• 135761-42-1 tris(4-pentafluoroethylphenyl)amine 
• 118996-38-6 4,4’,4’’-tricarboxyltriphenylamine 
• 2229-07-4 methyl radical 
• 124-38-9 carbon dioxide 
• 91-20-3 naphthalene 
• 103273-57-0 trans-2,3-Dibrom-1,2,3,4-tetrahydronaphthalin 
• 134567-86-5 trans-2-Brom-3-chlor-1,2,3,4-tetrahydronaphthalin 
• 113664-28-1 4-cyano-4′,4′′-dibromotriphenylamine 
• 113678-54-9 (2-cyano-4-bromophenyl)-bis(4-bromophenyl)amine 
• 105864-92-4 (2-acetoxy-4-bromophenyl)-bis(4-bromophenyl)amine 
• 5489-72-5 Tris(2,4-dibromophenyl)amine 
• 73087-83-9 3,6-dibromo-9-(4-bromophenyl)-9H-carbazole 
• 67974-40-7 tris(4-bromophenyl)ammoniumyl hexafluorophosphate 

Relevant articles and documents

The Reaction of 2,3-Diazabicyclooct-2-ene with Stable Cation Radical Salts

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Enhanced Electron Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analogue

Reactions of N,N-dimethylaniline (DMA) with nonheme iron(IV)-oxo and iron(IV)-tosylimido complexes occur via different mechanisms, such as an N-demethylation of DMA by a nonheme iron(IV)-oxo complex or an electron transfer dimerization of DMA by a nonheme iron(IV)-tosylimido complex. The change in the reaction mechanism results from the greatly enhanced electron transfer reactivity of the iron(IV)-tosylimido complex, such as the much more positive one-electron reduction potential and the smaller reorganization energy during electron transfer, as compared to the electron transfer properties of the corresponding iron(IV)-oxo complex.

Synthesis and chemosensory properties of triphenylamine-substituted conjugated polyfluorene containing a terminal di(2-picolyl)amine moiety

This paper describes the synthesis of a triphenylamine-substituted alternating conjugated polyfluorene (PFAD) containing a pendant terminal di(2-picolyl)amine (DPA) group through the Heck coupling reaction. We examined the effect of DPA units on the senso

Synthesis and optoelectronic properties of thermally cross-linkable hole-transporting poly(fluorene-co-triphenylamine)

This paper describes the synthesis of a new thermally cross-linkable hole-transporting poly(fluorene-co-triphenylamine) (PFTV) by Suzuki coupling reaction and its application in polymer light-emitting diodes (PLEDs). The characteristics of PFTV were analy

In situ generated tris(p-bromophenyl)amine radical cation promoted electron transfer reaction of cyclopropyl silyl ethers

Tris(p-bromophenyl)aminium hexachloroantimonate and perchlorate were utilized to promote the oxidative ring-opening reaction of cyclopropyl silyl ethers giving ring-expanded ketones. Exploration of salt quantity effect on the reaction allowed us to hypoth

Synthetic method of phenylacetonitrile-based aromatic mechanical response fluorescent material

The invention discloses a synthetic method of a phenylacetonitrile-based aromatic mechanical response fluorescent material, which comprises the following steps: reacting 1 part of brominated intermediate R with 1-4 parts of 4-cyanomethylphenylboronic acid

Phosphoric acid delayed-fluorescence material and preparation method thereof

The invention relates to the technical field of electroluminescence, in particular to a phosphoric acid delayed-fluorescence material and a preparation method thereof. The phosphoric acid delayed-fluorescent material provided by the invention has a structural formula as shown in a formula (I) which is described in the specification. The invention also provides a preparation method of the phosphoric acid delayed-fluorescence material. The preparation method comprises the following step: subjecting a compound as shown in a formula (II) to reacting with a compound as shown in the formula (III) to prepare the compound as shown in the formula (I). The phosphoric acid delayed-fluorescent material and a preparation method thereof provided by the invention solve the technical problems that existing red TADF materials are relatively difficult to synthesize and device efficiency is not high.

Anthracene-triphenylamine-based platinum(II) metallacages as synthetic light-harvesting assembly

Two trigonal prismatic metallacages 1 and 2 bearing triphenylamine and anthracene moieties are designed and synthesized to fabricate artificial light-harvesting systems (LHSs). These two cages are prepared via the coordination-driven self-assembly of two