434957-51-4

Basic information

• Product Name: 2-Propenoic acid, 3-(acetylamino)-3-(4-chlorophenyl)-, ethyl ester, (2Z)-
• CAS NO: 434957-51-4
• Molecular Formula: C13H14ClNO3
• Molecular Weight: 267.712
• Mol File: 434957-51-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(acetylamino)-3-(4-chlorophenyl)-, ethyl ester, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(acetylamino)-3-(4-chlorophenyl)-, ethyl ester, (2Z)-(434957-51-4)
• EPA Substance Registry System: 2-Propenoic acid, 3-(acetylamino)-3-(4-chlorophenyl)-, ethyl ester, (2Z)-(434957-51-4)

Safety Data

• Hazardous Substances Data: 434957-51-4(Hazardous Substances Data)

Upstream product

• 2881-63-2 ethyl (4-chlorobenzoyl)acetate 

Downstream Products

• 844439-52-7 (S)-ethyl 3-acetamido-3-(4-chlorophenyl)-propanoate 
• 844439-52-7 (R)-ethyl 3-acetamido-3-(4-chlorophenyl)-propanoate 

Relevant articles and documents

Highly effective chiral ortho-substituted BINAPO ligands (o-BINAPO): Applications in Ru-catalyzed asymmetric hydrogenations of β-aryl-substituted β-(acylamino)acrylates and β-keto esters

A novel family of chiral ortho-substituted BINAPO ligands (o-BINAPO) were synthesized from BINOL, and their Ru complexes were highly efficient catalysts for asymmetric hydrogenation of β-aryl-substituted β-(acylamino)acrylates and β-aryl-substituted β-keto esters. The Ru-bisphosphinite catalysts can tolerate an E/Z mixture of β-aryl-substituted β-(acylamino)acrylates. These highly enantioselective hydrogenations provide a useful way to prepare β-aryl-substituted β-amino acids and β-hydroxyl acids. Copyright