444144-88-1

Basic information

• Product Name: Benzene, 1-nitro-3-(2-nitro-1-phenylethyl)-
• CAS NO: 444144-88-1
• Molecular Formula: C14H12N2O4
• Molecular Weight: 272.26
• Mol File: 444144-88-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-3-(2-nitro-1-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-3-(2-nitro-1-phenylethyl)-(444144-88-1)
• EPA Substance Registry System: Benzene, 1-nitro-3-(2-nitro-1-phenylethyl)-(444144-88-1)

Safety Data

• Hazardous Substances Data: 444144-88-1(Hazardous Substances Data)

Upstream product

• 882-26-8 (E)-1-nitro-3-(2-nitrovinyl)benzene 
• 1135-99-5 diphenyltin(IV) dichloride 
• 595-90-4 tetraphenyltin(IV) 

Downstream Products

• 20105-50-4 (+/-)-2-(m-Amino-phenyl)-2-phenyl-ethylamin 

Relevant articles and documents

Palladium(II)-catalyzed Michael-type hydroarylation of nitroalkenes using aryltins and sodium tetraarylborates

A variety of aryltin compounds and sodium tetraarylborates can be employed for Michael-type hydroarylation reactions of nitroalkenes to afford β-arylnitroalkanes in moderate to good yields in the presence of either LiCl, MgCl2, or CaCl2 and a catalytic amount of palladium(II) salt (0.05 molar amount) in acetic acid. Results show that 50-70% of aryl groups out of all in these aryl compounds can be transferred to the products in this hydroarylation. The addition of a catalytic amount (0.05-0.10 molar amount) of a Lewis acid chloride, BiCl3 or SbCl3, much improves the product yield in some cases.