4561-70-0Relevant articles and documents
The Regio- and Stereocontrolled Ring Opening of Heteroarylglycidates with Nitrogen Nucleophiles
Alcaide, Benito,Biurrun, Cristina,Martinez, Ana,Plumet, Joaquin
, p. 5417 - 5420 (2007/10/02)
The ring opening of furyl and thienylglycidates with benzylamine and trimethylsilyl azide have been studied considering both the regio- and stereoselectivity of the reaction.
Epoxide Synthesis in Interfacial Solid-Liquid Conditions
Borredon, E.,Clavellinas, F.,Delmas, M.,Gaset, A.,Sinisterra, J. V.
, p. 501 - 504 (2007/10/02)
In this paper an analysis of the factors responsible for discrimination among differing structures of organic reagents by the microcrystalline structure of solids is presented.As a vehicle of this study, the epoxide synthesis using three sulfur ylide precursors (sulfonium and sulfoxonium salts) and four microcrystalline solids was investigated.Neither the surface area nor the number of active sites at the solid surface control the epoxide yield.It appears that the cell lattice of the solid determines the ylide structure, its nucleophilicity, and thus the reaction yield.
NEW STEREOSELECTIVE SYNTHESIS OF EPOXIDES FROM ALDEHYDES BY SOLID-LIQUID PHASE TRANSFER PROCESS IN A WEAKLY HYDRATED ORGANIC MEDIUM
Koua, K. Oi,Borredon, M. E.,Delmas, M.,Gaset, A.
, p. 1593 - 1602 (2007/10/02)
The use of potassium carbonate leads to a stereoselective synthesis of epoxyesters in the presence of substituted thiolanium salts and a carbonyl compound in a solid-liquid low hydrated organic medium.