463962-26-7Relevant articles and documents
S-Thioacyldithiophosphates in the synthesis of thiohydroxamic acids and O-thioacylhydroxylamines
Doszczak, Leszek,Rachon, Janusz
, p. 1047 - 1052 (2007/10/03)
S-Thioacyldithiophosphates proved to be excellent thioacylating agents. They are easily available from carboxylic acids. Due to their low reactivity towards oxygen nucleophiles and high reactivity towards nitrogen ones they found application in the synthe
New, efficient and chemoselective method of thioacylation, starting from carboxylic acids
Doszczak,Rachon
, p. 2093 - 2094 (2007/10/03)
S-Acylation of dithiophosphoric acids yields mixed anhydrides 3; they readily isomerize to O-thioacyl 4 and S-thioacyl monothiophosphates 5, which treated with the excess of dithiophosphoric acid 2 can be easily converted into thioacyl dithiophosphates 6, excellent thioacylating reagents.