4663-36-9

Basic information

• Product Name: 1,1,3-Triphenyl-2-propen-1-ol
• Synonyms: 1,1,3-Triphenyl-2-propen-1-ol
• CAS NO: 4663-36-9
• Molecular Formula: C₂₁H₁₈O
• Molecular Weight: 286.37
• Mol File: 4663-36-9.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 463.4°C at 760 mmHg
• Flash Point: 184.5°C
• Appearance: /
• Density: 1.133g/cm³
• Vapor Pressure: 2.2E-09mmHg at 25°C
• Refractive Index: 1.65
• CAS DataBase Reference: 1,1,3-Triphenyl-2-propen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,3-Triphenyl-2-propen-1-ol(4663-36-9)
• EPA Substance Registry System: 1,1,3-Triphenyl-2-propen-1-ol(4663-36-9)

Safety Data

• Hazardous Substances Data: 4663-36-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 1507, 1994 DOI: 10.1016/S0040-4039(00)76744-X

InChI:InChI=1/C21H18O/c22-21(19-12-6-2-7-13-19,20-14-8-3-9-15-20)17-16-18-10-4-1-5-11-18/h1-17,22H/b17-16+

Upstream product

• 119-61-9 benzophenone 
• 60-29-7 diethyl ether 
• 737-79-1 1,1,3,-triphenyl-1-propene 
• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 591-51-5 phenyllithium 
• 94-41-7 benzalacetophenone 
• 591-50-4 iodobenzene 
• 26138-28-3 phenylytterbium iodide 
• 103-64-0 bromostyrene 
• 98-80-6 phenylboronic acid 

Downstream Products

• 4467-88-3 1,3-diphenylindene 
• 408351-80-4 3-chloro-1,1,3-triphenyl-propene 
• 6817-43-2 hexa-1,5-diene-1,1,3,4,6,6-hexaylhexabenzene 
• 62214-54-4 1-methoxy-1-1.3t-triphenyl-propene-⁽²⁾ 

Relevant articles and documents

FeCl3-catalyzed 1,2-addition reactions of aryl aldehydes with arylboronic acids

(Chemical Equation Presented) A novel protocol for the 1,2-addition reactions of electron-deficient aryl aldehydes with arylboronic acids using an inexpensive and environmentally benign iron catalyst is reported. In the presence of FeCl3 and 2-

Reactions of Carbonyl Compounds with Grignard Reagents in the Presence of Cerium Chloride

The addition of Grignard reagents to ketones is significantly enhanced by cerium chloride with remarkable supression of side reactions, particularly enolization.Some esters, which are prone to side reactions, also react readily with Grignard reagents in the presence of cerium chloride to give normal reaction products in reasonable to high yields.

CERIUM CHLORIDE-PROMOTED NUCLEOPHILIC ADDITION OF GRIGNARD REAGENTS TO KETONES AN EFFICIENT METHOD FOR THE SYNTHESIS OF TERTIARY ALCOHOLS

In the presence of anhydrous cerium(III) chloride, Grignard reagents react with ketones to afford addition products in high yields, even though the substrates are susceptible to abnormal reactions with Grignard reagents alone.