467430-25-7

Basic information

• Product Name: [Ru(BINAP)H(η6-benzene)]OTf
• CAS NO: 467430-25-7
• Molecular Weight: 951.948
• Mol File: 467430-25-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(BINAP)H(η6-benzene)]OTf(CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(BINAP)H(η6-benzene)]OTf(467430-25-7)
• EPA Substance Registry System: [Ru(BINAP)H(η6-benzene)]OTf(467430-25-7)

Safety Data

• Hazardous Substances Data: 467430-25-7(Hazardous Substances Data)

Upstream product

• 114818-52-9 Ru(OCOCH₃)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)} 
• 1493-13-6 trifluorormethanesulfonic acid 
• 71-43-2 benzene 

Relevant articles and documents

A facile synthesis of a wide variety of cationic ruthenium hydrido-arene complexes of binap (=1,1′-binaphthalene-2,2′-diylbis(diphenylphosphane)) and meo-biphep (=6,6′-dimethoxybiphenyl-2,2′-diylbis(diphenylphosphane))

A straightforward high-yield synthetic route to the cationic hydrido-arene complexes [RuH(η6-arene)(binap or MeO-biphep)](CF3SO3), with a variety of arenes containing both donor and acceptor substituents, is described. 13C-NMR Data for these complexes are reported. Several of these Ru-complexes have been used as transfer-hydrogenation catalysts in the reduction of acetophenone.