48121-13-7

Basic information

• Product Name: Copper, [(4-methoxyphenyl)ethynyl]-
• CAS NO: 48121-13-7
• Molecular Formula: C9H7CuO
• Molecular Weight: 194.7
• Mol File: 48121-13-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Copper, [(4-methoxyphenyl)ethynyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Copper, [(4-methoxyphenyl)ethynyl]-(48121-13-7)
• EPA Substance Registry System: Copper, [(4-methoxyphenyl)ethynyl]-(48121-13-7)

Safety Data

• Hazardous Substances Data: 48121-13-7(Hazardous Substances Data)

Upstream product

• 12775-96-1 copper 
• 768-60-5 4-methoxyphenylacetylen 
• 696-62-8 para-iodoanisole 
• 3989-14-8 (4-methoxyphenylethynyl)trimethylsilane 
• 7758-99-8 copper(II) sulfate 
• 7681-65-4 copper(l) iodide 
• 830-09-1 3-(4'-methoxyphenyl)propenoic acid 
• 31448-61-0 2,3-dibromo-3-(4-methoxy-phenyl)-propionic acid 
• 27570-08-7 4-(2-bromo-vinyl)-anisole 

Downstream Products

• 521944-76-3 4-(4-methoxy-phenylethynyl)-1-methyl-1H-pyrazole-3-carboxylic acid methyl ester 
• 521944-74-1 3-(4-methoxy-phenylethynyl)-1,5-dimethyl-1H-pyrazole-4-carboxylic acid methyl ester 
• 54737-59-6 1-[4-(4-Methoxy-phenylethynyl)-phenyl]-1-methyl-ethylamine 
• 4767-61-7 3-(4-methoxybenzylidene)phthalide 
• 176100-87-1 (4-methoxy-phenylethynyl)-phosphonic acid diethyl ester 
• 691904-52-6 methyl 2-(4-methoxyphenyl)-5-benzofuranpropanoate 
• 1310329-75-9 [2-(4-methoxyphenyl)ethynyl]diphenylphosphine oxide 
• 1208365-04-1 1,2,3,4,5-pentafluoro-6-(2-(4-methoxyphenyl)ethynyl)benzene 
• 1226889-63-9 2-[(4-methoxyphenyl)ethynyl]benzoxazole 
• 82203-83-6 1-(p-methoxyphenyl)-3,3,3-trifluoropropyne 

Relevant articles and documents

Blue-Emitting Arylalkynyl Naphthalene Derivatives via a Hexadehydro-Diels-Alder Cascade Reaction

We describe here three alkynyl substituted naphthalenes that display promising luminescence characteristics. Each compound is easily and efficiently synthesized in three steps by capitalizing on the hexadehydro-Diels-Alder (HDDA) cycloisomerization reacti

Copper-Catalyzed Photoinduced Enantioselective Dual Carbofunctionalization of Alkenes

A photoinduced, copper-catalyzed, highly enantioselective dual alkylation/arylation and alkynylation of alkene is reported. A single chiral copper(I) complex serves to enable photoredox catalysis and induce enantioselectivity during the reaction. This reaction couples three different components under mild reaction conditions, exhibits a broad substrate scope, and provides facile access to chiral propargylic systems, including those featuring valuable fluorinated substituents.

Direct Metal-Free Entry to Aminocyclobutenes or Aminocyclobutenols from Ynamides: Synthetic Applications

The [2+2] cycloaddition of ynamides with the highly polarized reagent Tf2C=CH2has been developed to regioselectively afford bis(triflyl)aminocyclobutenes in the absence of catalyst under mild conditions. Incidentally, with the ynamides bearing electron-rich aromatic rings at the C-terminal, an interesting reactivity switch was observed; a cyclization/hydroxylation sequence yielded 2-amino-3-(triflyl)cyclobut-2-enols. Aminocyclobutene construction with addition of alcohols resulted in the formation of aminocyclobutenyl ethers through a cyclization/hydroalkoxylation process. Moreover, the utility of functionalized aminocyclobutenes as precursors for further elaboration was demonstrated with the preparation of α-amino-β,γ-unsaturated ketones and 3-(triflyl)buta-1,3-dien-2-amines through 4 π-electrocyclic ring opening.