49642-49-1

Basic information

• Product Name: Octanal, 2-methyl-, (R)-
• CAS NO: 49642-49-1
• Molecular Formula: C9H18O
• Molecular Weight: 142.241
• Mol File: 49642-49-1.mol
• Article Data: 233

Chemical Properties

• CAS DataBase Reference: Octanal, 2-methyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Octanal, 2-methyl-, (R)-(49642-49-1)
• EPA Substance Registry System: Octanal, 2-methyl-, (R)-(49642-49-1)

Safety Data

• Hazardous Substances Data: 49642-49-1(Hazardous Substances Data)

Upstream product

• 818-81-5 2-methyloctan-1-ol 
• 3004-93-1 2-methyloctanoic acid 
• 78-85-3 2-methylpropenal 
• 64889-46-9 n-pentylcopper 
• 557-35-7 2-bromooctane 
• 111-87-5 octanol 
• 64-17-5 ethanol 
• 111-66-0 oct-1-ene 
• 201230-82-2 carbon monoxide 
• 13389-42-9 trans-2-Octene 
• 127839-46-7 (2RS)-1-bromo-2-methyloctane 
• 446276-90-0 ((S)-2-Methoxymethyl-pyrrolidin-1-yl)-[(S)-2-methyl-oct-(E)-ylidene]-amine 
• 63262-78-2 ((S)-2-methoxymethyl-pyrrolidin-1-yl)-((R)-2-methyl-octylidene)-amine 
• 50-00-0 formaldehyd 

Downstream Products

• 818-81-5 2-methyloctan-1-ol 
• 117184-53-9 6'-epi-Aranorosin 
• 117184-53-9 Aranorosin 
• 229334-21-8 Gymnastatin H 
• 1269425-15-1 methyl 2-[(2E,4E)-4,6-dimethyldodeca-2,4-dienamido]-3-(4-t-butyldimethylsilyloxyphenyl)-propanoate 
• 1453811-61-4 (2S,4S,5S,6S)-5-hydroxy-1-(4-methoxybenzyloxy)-2,4,6-trimethyldodecan-3-one 
• 1453811-56-7 ((2R,3R,4S,6S)-1-(2-tert-butoxy-2-oxoethylamino)-2,4,6-trimethyl-1-oxododecan-3-yl) (S)-2-(benzyloxycarbonylamino)propanoate 
• 1453811-68-1 (S)-((3S,4R,5S,7S)-3,5,7-trimethyltridec-1-en-4-yl) 2-(benzyloxycarbonylamino)propanoate 
• 1453811-67-0 1-methoxy-4-(((3S,4R,5S,7S)-3,5,7-trimethyltridec-1-en-4-yloxy)methyl)benzene 
• 1453811-66-9 (2S,3R,4S,6S)-3-(4-methoxybenzyloxy)-2,4,6-trimethyldodecan-1-ol 
• 1453811-65-8 (4R,5S)-2-(4-methoxyphenyl)-5-methyl-4-((2S,4S)-4-methyldecan-2-yl)-1,3-dioxane 
• 1453811-64-7 O-(2R,3S,4S)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-4-methyldecan-3-yl (S)-methyl carbonodithioate 
• 1453811-60-3 (2S,3S,4S)-2-((4S,5S)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-4-methyldecan-3-ol 
• 1453811-63-6 (2S,3S,4S,5S,6S)-1-(4-methoxybenzyloxy)-2,4,6-trimethyldodecane-3,5-diol 

Relevant articles and documents

Enantiopure Acetals of α-Alkynyl Carbonyl Compounds: Organoaluminum-Mediated 1,2-Shift of Cobalt-Complexed Alkynyl Group with Concomitant Capture by a Nucleophile

Upon treatment with the organoaluminum-based combination of Lewis acid and nucleophile, chiral mesyloxy acetal having a Co-complexed alkynyl group undergoes stereospecific 1,2-shift of the complexed alkynyl and the concomitant attack of the ligand R of the organoaluminum reagent. Decomplexation of the products with CAN gives the chiral acetals of α-alkynyl carbonyl compounds in enantiomerically pure form in high yields.

Chemo- And regioselective hydroformylation of alkenes with CO2/H2over a bifunctional catalyst

As is well known, CO2 is an attractive renewable C1 resource and H2 is a cheap and clean reductant. Combining CO2 and H2 to prepare building blocks for high-value-added products is an attractive yet challenging topic in green chemistry. A general and selective rhodium-catalyzed hydroformylation of alkenes using CO2/H2 as a syngas surrogate is described here. With this protocol, the desired aldehydes can be obtained in up to 97% yield with 93/7 regioselectivity under mild reaction conditions (25 bar and 80 °C). The key to success is the use of a bifunctional Rh/PTA catalyst (PTA: 1,3,5-triaza-7-phosphaadamantane), which facilitates both CO2 hydrogenation and hydroformylation. Notably, monodentate PTA exhibited better activity and regioselectivity than common bidentate ligands, which might be ascribed to its built-in basic site and tris-chelated mode. Mechanistic studies indicate that the transformation proceeds through cascade steps, involving free HCOOH production through CO2 hydrogenation, fast release of CO, and rhodium-catalyzed conventional hydroformylation. Moreover, the unconventional hydroformylation pathway, in which HCOOAc acts as a direct C1 source, has also been proved to be feasible with superior regioselectivity to that of the CO pathway.

Methyl-modified cage-type phosphorus ligand and preparation method thereof Preparation method and application thereof

The invention discloses a methyl-modified cage-type phosphorus ligand, a preparation method and application thereof, in particular to a synthesis design, wherein methyl is further introduced on a phenyl ring of triphenylphosphine, and a methyl-modified cage-type phosphorus ligand is synthesized, and when a methyl meta-substituted cage-type phosphorus ligand is used as a hydroformylation reaction catalyst the proportion of n-structural aldehyde and isomeric aldehyde is 2.6. TOF-1 The methyl-substituted cage-type phosphorus ligand is excellent in performance, stable in property and recyclable, has excellent substrate applicability in the hydroformylation catalytic reaction, has a good industrial application prospect, and has very important significance in metal organic catalysis.