497069-15-5

Basic information

• Product Name: Benzoic acid, 3-hydroxy-5-(2-propenyloxy)-, ethyl ester
• CAS NO: 497069-15-5
• Molecular Formula: C12H14O4
• Molecular Weight: 222.241
• Mol File: 497069-15-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 3-hydroxy-5-(2-propenyloxy)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 3-hydroxy-5-(2-propenyloxy)-, ethyl ester(497069-15-5)
• EPA Substance Registry System: Benzoic acid, 3-hydroxy-5-(2-propenyloxy)-, ethyl ester(497069-15-5)

Safety Data

• Hazardous Substances Data: 497069-15-5(Hazardous Substances Data)

Upstream product

• 99-10-5 3,5-Dihydroxybenzoic acid 
• 4142-98-7 ethyl 3,5-dihydroxybenzoate 
• 106-95-6 allyl bromide 

Downstream Products

• 1026348-17-3 3-allyloxy-5-(4-tert-butyl-benzyloxy)-benzoic acid ethyl ester 
• 497069-05-3 ethyl-3-benzyloxy-5-allyloxy-benzoate 
• 474960-23-1 3-allyloxy-5-hydroxybenzyl alcohol 
• 692204-40-3 3-benzyloxy-5-(3-hydroxy-propoxy)-benzoic acid ethyl ester 
• 474960-29-7 3-p-tert-butylbenzyloxy-5-hydroxybenzyl alcohol 
• 474960-25-3 3-allyloxy-5-p-tert-butylbenzyloxybenzyl alcohol 
• 474960-30-0 3-m-methylbenzyloxy-5-hydroxybenzyl alcohol 
• 474960-28-6 3-O-methylbenzyloxy-5-hydroxybenzyl alcohol 
• 474960-24-2 3-allyloxy-5-O-methylbenzyloxybenzyl alcohol 
• 474960-26-4 3-(m-methylbenzyloxy)-5-allyloxybenzyl alcohol 
• 474960-31-1 3-decyloxy-5-hydroxybenzyl alcohol 
• 474960-36-6 3-O-methylbenzyloxy-5-p-bromobenzyloxybenzyl bromide 
• 474960-32-2 3-O-methylbenzyloxy-5-p-bromobenzyloxybenzyl alcohol 
• 474960-27-5 3-allyloxy-5-decyloxybenzyl alcohol 

Relevant articles and documents

A mild deprotection strategy for allyl-protecting groups and its implications in sequence specific dendrimer synthesis

A mild deprotection strategy for allyl ethers under basic conditions in the presence of a palladium catalyst is described. Under these conditions, aryl allyl ethers can be cleaved selectively in the presence of alkyl allyl ethers. These conditions are also effective in the deprotection of allyloxycarbonyl groups. The utility of the current methodology in sequence specific dendrimer synthesis is demonstrated.

Functional group diversity in dendrimers

(graph presented) A methodology for synthesizing dendrons with different peripheral functionalities is described. The benzyl ether-based dendrons reported here were synthesized using allyl and methoxymethyl ether-based protection-deprotection strategies.