49764-18-3

Basic information

• Product Name: di-(1-adamantyl) ether
• Synonyms: di-(1-adamantyl) ether
• CAS NO: 49764-18-3
• Molecular Weight: 286.458
• Mol File: 49764-18-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: di-(1-adamantyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: di-(1-adamantyl) ether(49764-18-3)
• EPA Substance Registry System: di-(1-adamantyl) ether(49764-18-3)

Safety Data

• Hazardous Substances Data: 49764-18-3(Hazardous Substances Data)

Upstream product

• 3398-16-1 4-Bromo-3,5-dimethylpyrazole 
• 768-93-4 1-iodoadamantane 
• 15878-00-9 4-chloro-1H-pyrazole 
• 768-90-1 1-Adamantyl bromide 
• 815-57-6 3-Methyl-2,4-pentanedione 
• 25236-60-6 1-adamantyl methanesulfonate 
• 3034-38-6 1H-4⁽⁵⁾-nitroimidazole 
• 2075-46-9 4-nitro-1H-pyrazole 

Relevant articles and documents

Oxidative alkylation of azoles: VII. Adamantylation of azoles via oxidative generation of 1-adamantyl cations

A procedure has been developed for oxidative N-adamantylation of azoles with 1-iodoadamantane in the presence of chromium(IV) oxide or iodine(V) oxide. The procedure is applicable to azoles whose pKBH+ value does not exceed 2.26. * For communication VI, see [1].

Reactions of copper(II) β-diketonates under free radical conditions. Preparation of highly congested β-diketones

Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.