498554-05-5

Basic information

• Product Name: (1R,3R,6R,9R,10S)-9,10-bis(tert-butyldimethylsilyloxy)-8-methylene-3-phenyl-2,4,7-trioxabicyclo[4.4.0]decane
• Synonyms: (1R,3R,6R,9R,10S)-9,10-bis(tert-butyldimethylsilyloxy)-8-methylene-3-phenyl-2,4,7-trioxabicyclo[4.4.0]decane
• CAS NO: 498554-05-5
• Molecular Weight: 492.803
• Mol File: 498554-05-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,3R,6R,9R,10S)-9,10-bis(tert-butyldimethylsilyloxy)-8-methylene-3-phenyl-2,4,7-trioxabicyclo[4.4.0]decane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3R,6R,9R,10S)-9,10-bis(tert-butyldimethylsilyloxy)-8-methylene-3-phenyl-2,4,7-trioxabicyclo[4.4.0]decane(498554-05-5)
• EPA Substance Registry System: (1R,3R,6R,9R,10S)-9,10-bis(tert-butyldimethylsilyloxy)-8-methylene-3-phenyl-2,4,7-trioxabicyclo[4.4.0]decane(498554-05-5)

Safety Data

• Hazardous Substances Data: 498554-05-5(Hazardous Substances Data)

Upstream product

• 113533-88-3 4,6-O-benzylidene-2,3-bis-O-(tert-butyldimethylsilyl)-D-glucopyranose 
• 75-24-1 trimethylaluminum 
• 498554-04-4 4,6-O-benzylidene-2,3-bis-O-(tert-butyldimethylsilyl)-D-glucono-1,5-lactone 

Relevant articles and documents

Synthesis of the AB-ring segment for the convergent construction of the left half in ciguatoxin

The synthesis of the AB-ring segment aiming at the convergent construction of the left half in ciguatoxin (CTX1B) has been achieved by a strategy based on ring-closing metathesis (RCM) and diastereocontrolled hydroboration to cyclic vinyl ethers.