501-58-6Relevant articles and documents
Well-defined vanadium organoazide complexes and their conversion to terminal vanadium imides: Structural snapshots and evidence for a nitrene capture mechanism
Harman, W. Hill,Lichterman, Michael F.,Piro, Nicholas A.,Chang, Christopher J.
, p. 10037 - 10042 (2012)
We report the synthesis and structural characterization of a family of well-defined organoazide complexes supported by a three-fold-symmetric pyrrolide scaffold and their conversion to the corresponding terminal imido congeners. Kinetic measurements on a
Manganese Catalyzed Hydrogenation of Azo (N=N) Bonds to Amines
Ben-David, Yehoshoa,Das, Uttam Kumar,Diskin-Posner, Yael,Kar, Sayan,Milstein, David
supporting information, p. 3744 - 3749 (2021/07/09)
We report the first example of homogeneously catalyzed hydrogenation of the N=N bond of azo compounds using a complex of an earth-abundant-metal. The hydrogenation reaction is catalyzed by a manganese pincer complex, proceeds under mild conditions, and yields amines, which makes this methodology a sustainable alternative route for the conversion of azo compounds. A plausible mechanism involving metal-ligand cooperation and hydrazine intermediacy is proposed based on mechanistic studies. (Figure presented.).
A synthetic method of aromatic azo compounds
-
Paragraph 0054-0061, (2022/01/05)
The present invention belongs to the field of azo compound technology, discloses a method of synthesis of an aromatic azo compound. The present invention is an aromatic amine and a catalyst massager ratio 1: 0.05 ~ 0.06 mixed, at 95 ~ 110 ° C reaction 22