503299-61-4Relevant articles and documents
Stereoselective preparation of (Z)-γ-silyl-γ,δ-unsaturated ketones and their application in the synthesis of 1,4-Diketones
Zheng, Weixin,Huang, Xian
, p. 2497 - 2502 (2007/10/03)
Hydrozirconation reaction of alkynylsilanes 1 followed by Michael addition to α,β-unsaturated ketones in the presence of CuBr Me2S complex produced (Z)-γ-silyl-γ,δ-unsaturated ketones 3 stereoselectively. 1,4-Diketones were prepared via epoxidation and hydrolysis of 3.