50337-59-2

Basic information

• Product Name: Benzene, (cyclopropylsulfinyl)-
• Synonyms: phenyl cyclopropyl sulfoxide;cyclopropyl phenyl sulfoxide
• CAS NO: 50337-59-2
• Molecular Formula: C9H10OS
• Molecular Weight: 166.244
• Mol File: 50337-59-2.mol
• Article Data: 46

Chemical Properties

• CAS DataBase Reference: Benzene, (cyclopropylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (cyclopropylsulfinyl)-(50337-59-2)
• EPA Substance Registry System: Benzene, (cyclopropylsulfinyl)-(50337-59-2)

Safety Data

• Hazardous Substances Data: 50337-59-2(Hazardous Substances Data)

Upstream product

• 14633-54-6 cyclopropylphenylsulfide 
• 108-98-5 thiophenol 
• 13033-58-4 3-Chloropropyl Phenyl Sulfoxide 
• 100-52-7 benzaldehyde 

Downstream Products

• 33381-21-4 Cyclopropyl(dimethylamino)phenyloxosulfonium tetrafluoroborate 
• 126582-49-8 1-(1-Phenylsulfanyl-cyclopropyl)-pentan-1-ol 
• 63365-90-2 (E)-1-(1-Phenylsulfanyl-cyclopropyl)-but-2-en-1-ol 
• 74032-40-9 1-<1-(phenylthio)cyclopropyl>-1-heptanol 
• 83022-84-8 (1-Octyl-cyclopropylsulfanyl)-benzene 
• 83022-83-7 1-Butyl-cyclopropyl phenyl sulfide 
• 63048-70-4 2-Methyl-1-(1-phenylsulfanyl-cyclopropyl)-cyclohexanol 
• 63048-69-1 Cyclohex-3'-en-1'-yl-(1''-phenylthio-cycloprop-1''-yl)-methanol 
• 63048-67-9 2-<1-(phenylthio)cyclopropyl>-2-propanol 
• 63365-75-3 2-(1-Phenylsulfanyl-cyclopropyl)-octan-2-ol 
• 70042-50-1 1-<1-(phenylthio)cyclopropyl>cyclohexanol 
• 70042-49-8 α-<1-(phenylthio)cyclopropyl>benzyl alcohol 
• 7632-57-7 diphenylmethylenecyclopropene 
• 4170-69-8 isopropyl phenyl sulfoxide 

Relevant articles and documents

Catalyst-free visible light-mediated selective oxidation of sulfides into sulfoxides under clean conditions

A facile and efficient visible-light-mediated method for directly converting sulfides into sulfoxides under clean conditions without using any photocatalysts is reported. This method exhibited favourable compatibility with functional groups and afforded a series of sulfoxides with high selectivity and yields. Moreover, in order to shed more light on such a transformation, detailed mechanism studies were carried out both experimentally and theoretically. The readily accessible, low-cost and eco-friendly nature of the developed method will endow it with attractive applications in chemical synthesis.

Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction. This journal is

Flow Electrosynthesis of Sulfoxides, Sulfones, and Sulfoximines without Supporting Electrolytes

An efficient electrochemical flow process for the selective oxidation of sulfides to sulfoxides and sulfones and of sulfoxides toN-cyanosulfoximines has been developed. In total, 69 examples of sulfoxides, sulfones, andN-cyanosulfoximines have been synthesized in good to excellent yields and with high current efficiencies. The synthesis was assisted and facilitated through a supporting electrolyte-free, fully automated electrochemical protocol that highlights the advantages of flow electrolysis.