504422-60-0

Basic information

• Product Name: 2,6-dibromo-3,5-dimethoxybenzaldehyde
• Synonyms: 2,6-dibromo-3,5-dimethoxybenzaldehyde
• CAS NO: 504422-60-0
• Molecular Weight: 323.969
• Mol File: 504422-60-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,6-dibromo-3,5-dimethoxybenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-dibromo-3,5-dimethoxybenzaldehyde(504422-60-0)
• EPA Substance Registry System: 2,6-dibromo-3,5-dimethoxybenzaldehyde(504422-60-0)

Safety Data

• Hazardous Substances Data: 504422-60-0(Hazardous Substances Data)

Upstream product

• 7311-34-4 3,5-dimethoxybenzaldehdye 
• 85565-93-1 2-bromo-3,5-dimethoxy-benzaldehyde 

Downstream Products

• 1238891-87-6 (2,6-dibromo-3,5-dimethoxyphenyl)methanol 
• 64-18-6 formic acid 
• 24988-36-1 4,6-dibromo-1,3-dimethoxybenzene 
• 124480-97-3 2,6-dibromo-3,5-dimethoxy-benzoic acid 

Relevant articles and documents

Total synthesis of the biologically active, naturally occurring 3,4-dibromo-5-[2-bromo-3,4-dihydroxy-6-(methoxymethyl)benzyl]benzene-1,2-diol and regioselective O-demethylation of aryl methyl ethers

3,4-Dibromo-5-[2-bromo-3,4-dihydroxy-6-(methoxymethyl)benzyl]benzene-1, 2-diol (2), a natural product, has been synthesized for the first time starting from (3-bromo-4,5-dimethoxyphenyl)methanol (5) in five steps and with an overall yield of 34%. The reaction of some methoxymethyl-substituted aryl methyl ethers with BBr3, followed by the addition of MeOH, afforded the corresponding methoxymethyl-substituted arylphenols in high yields.

Pyridinium hydrobromide perbromide induces ipsobromodeformylation in o-hydroxy and o-methoxy substituted aromatic aldehydes

The reaction of o-hydroxy and o-methoxy substituted aromatic aldehydes with PHPB in pyridine gives aromatic bromination products including those arising from ipsobromodeformylation.