50622-67-8

Basic information

• Product Name: 5-acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester
• Synonyms: 5-acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester
• CAS NO: 50622-67-8
• Molecular Weight: 431.442
• Mol File: 50622-67-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 5-acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 5-acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester(50622-67-8)
• EPA Substance Registry System: 5-acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester(50622-67-8)

Safety Data

• Hazardous Substances Data: 50622-67-8(Hazardous Substances Data)

Upstream product

• 123-54-6 acetylacetone 
• 111017-83-5 ethyl 3-(2-ethoxycarbonylethyl)-4-methoxycarbonylmethyl-5-methylpyrrole-2-carboxylate 
• 111017-82-4 ethyl 5-methoxycarbonylmethyl-4,6-dioxoheptanoate 
• 74839-00-2 methyl 5-methyl-4,6-dioxoheptanoate 
• 39265-95-7 methyl 3-acetyl-4-oxopentanoate 
• 546-67-8 lead(IV) tetraacetate 
• 50622-64-5 benzyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-methylpyrrole-2-carboxylate 
• 127-09-3 sodium acetate 

Downstream Products

• 114091-96-2 3-(2-Methoxycarbonyl-ethyl)-5-[3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-5-methyl-1H-pyrrol-2-ylmethyl]-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 340156-78-7 3-(2-Methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-5-phenylsulfanylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 340156-77-6 benzyl 5-(2-mercaptobenzothiazolylmethyl)-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrole-2-carboxylate 
• 66365-74-0 benzyl 3,4'-bis(2-methoxycarbonylethyl)-3'-methoxycarbonylmethyl-4-methylpyrromethane-5'-carboxylate 
• 755714-87-5 C₅₅H₆₄N₅O₁₂⁽¹⁺⁾ 
• 111782-34-4 dibenzyl 1,5,8-tris-(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-2,3,6-trimethyl-b-oxobilane-1',8'-carboxylate 
• 111807-65-9 benzyl 4,4'-bis-(2-methoxycarbonylethyl)-3-methoxycarbonylmethyl-3'-methyl-2,2'-pyrromethane-5-carboxylate 
• 114091-95-1 2-[5-Benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-methoxycarbonylmethylpyrrol-2-ylmethyl]-4-(2-methoxycarbonylethyl)-3-methoxycarbonylmethyl-2-methyl-2H-pyrrole 
• 114091-94-0 3-(2-Methoxycarbonyl-ethyl)-5-[4-(2-methoxycarbonyl-ethyl)-3-methoxycarbonylmethyl-2-methyl-5-thioxo-2,5-dihydro-1H-pyrrol-2-ylmethyl]-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 114091-93-9 3-(2-Methoxycarbonyl-ethyl)-5-[4-(2-methoxycarbonyl-ethyl)-3-methoxycarbonylmethyl-2-methyl-5-oxo-2,5-dihydro-1H-pyrrol-2-ylmethyl]-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183061-68-9 (S)-3-[(3R,4R,5R)-4,5-((R)-Benzylidenedioxy)-2-oxotetrahydropyran-3-yloxycarbonylmethyl]-9-benzyloxycarbonyl-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-4-methyl-4,5-dihydrodipyrrin-1(10H)-one 

Relevant articles and documents

New method for the synthesis of pyrromethanes

Coupling reaction of 2-mercaptobenzothiazolylmethylpyrrole with α-free pyrrole in the presence of silver(I) triflate proceeds smoothly at room temperature to give a pyrromethane in excellent yield. The azafulvenium ion, an active form that reacts with α-f

BIOSYNTHESIS OF PORPHYRINS AND RELATED MACROCYCLES. PART 27. SYNTHESES OF MODIFIED HYDROXYMETHYLBILANES AND STUDIES OF THEIR CHEMICAL AND BIOLOGICAL PROPERTIES.

The biosynthetic pathway to uroporphyrinogen-III, the parent macrocycle for all the pigments of life, involves the formation and ring-closure of an hydroxymethylbilane.The non-enzymic ring-closure of this bilane is studied under different pH conditions.Also octamethyl esters of related bilanes are synthesised which have either a cyano or a methyl group blocking position-19 which is free on the terminal ring-D of the natural bilane.Studies are made of the ring-closure of these substituted bilanes under acidic conditions.The conclusion is reached that there is a strong preference for non-enzymic ring-closure of an hydroxymethylbilane to occur at the terminal carbon atom (position-19).The octa-acids derived from the cyano and methyl substituted bilanes inhibit the action of cosynthetase on the natural hydroxymethylbilane.