50640-97-6

Basic information

• Product Name: (R)-(+)-NN-dimethyl-1-p-methoxyphenylethylamine
• Synonyms: (R)-(+)-NN-dimethyl-1-p-methoxyphenylethylamine
• CAS NO: 50640-97-6
• Molecular Weight: 179.262
• Mol File: 50640-97-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-(+)-NN-dimethyl-1-p-methoxyphenylethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(+)-NN-dimethyl-1-p-methoxyphenylethylamine(50640-97-6)
• EPA Substance Registry System: (R)-(+)-NN-dimethyl-1-p-methoxyphenylethylamine(50640-97-6)

Safety Data

• Hazardous Substances Data: 50640-97-6(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 6298-96-0 1(R)-(4-methoxyphenyl)-ethylamine 

Downstream Products

• 87258-59-1 (S)-2-Dimethylamino-3-(4-methoxy-phenyl)-1-phenyl-butan-1-one 
• 87258-59-1 2-dimethylamino-3-p-methoxyphenyl-1-phenylbutan-1-one 
• 87258-47-7 (R)-(+)-NN-dimethyl-N-phenacyl-1-p-methoxyphenylethylammonium bromide 

Relevant articles and documents

Expanding the range of "Daniphos"-type P∩P- and P∩N-ligands: Synthesis and structural characterisation of new [(η6-arene)Cr(CO)3] complexes

New P∩P- and P∩N-ligands have been synthesised whose core structure is an [(η6-arene)Cr(CO)3] unit. These new ligands, which extend the range of "Daniphos" ligands, are endowed with central and planar chirality and have been prepared through a stereoselective synthetic strategy from optically pure benzylamines bearing a second substituent on the arene other than the benzyldimethylamino group. Because the two faces of unsymmetrically 1,2- and 1,3-disubstituted benzylamine are diastereotopic, which means that diastereomeric complexes arise upon coordination of the Cr(CO) 3 fragment to either of these two faces, the synthetic plan has been adjusted by exploiting the trimethylsilyl group as a temporary steric modulator in order to access both complexes with high diastereoselectivity. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.