50667-88-4Relevant articles and documents
Iron(II)/Persulfate Mediated Newman-Kwart Rearrangement
Gendron, Thibault,Pereira, Raul,Abdi, Hafsa Y.,Witney, Timothy H.,?rstad, Erik
, p. 274 - 278 (2020/01/02)
Herein, we report that iron(II)/ammonium persulfate in aqueous acetonitrile mediates the Newman-Kwart rearrangement of O-aryl carbamothioates. Electron-rich substrates react rapidly under moderate heating to afford the rearranged products in excellent yie
The Newman-Kwart rearrangement re-evaluated by microwave synthesis
Moseley, Jonathan D.,Sankey, Rosalind F.,Tang, Olivier N.,Gilday, John P.
, p. 4685 - 4689 (2007/10/03)
The Newman-Kwart rearrangement (NKR) has been re-evaluated by microwave heating. Microwave technology has proven to be ideal for investigating this high temperature rearrangement and facilitated the confirmation of many aspects of this valuable reaction.