50789-50-9

Basic information

• Product Name: (2S,R_S)-2-(anilino)-2-phenylethyl p-tolyl sulfoxide
• Synonyms: (2S,R_S)-2-(anilino)-2-phenylethyl p-tolyl sulfoxide
• CAS NO: 50789-50-9
• Molecular Weight: 335.47
• Mol File: 50789-50-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2S,R_S)-2-(anilino)-2-phenylethyl p-tolyl sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,R_S)-2-(anilino)-2-phenylethyl p-tolyl sulfoxide(50789-50-9)
• EPA Substance Registry System: (2S,R_S)-2-(anilino)-2-phenylethyl p-tolyl sulfoxide(50789-50-9)

Safety Data

• Hazardous Substances Data: 50789-50-9(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 1750-36-3 (E)-N-benzylidenebenzenamine 
• 538-51-2 benzylidene phenylamine 
• 112572-16-4 lithium (R_S)-(+)-methyl p-tolyl sulfoxide 

Downstream Products

• 779-54-4 (R)-phenyl-(1-phenylethyl)amine 

Relevant articles and documents

Diastereoselective addition of α-metalated sulfoxides to imines revisited: Mechanism, computational studies, and the effect of external chiral ligands

Some new results on asymmetric synthesis via the addition of α-metalated methyl tolyl sulfoxides to imines are presented. Good diastereoselectivity (up to >98% d.e. for product 3g) can be obtained under conditions of kinetic control (short reaction time,

Diastereoselective Kinetically and Thermodynamically Controlled Additions of (R)-(+)-Methyl p-Tolyl Sulphoxide Anion to Imines (Tolyl = C6H4Me)

The anion of (R)-(+)-methyl p-tolyl sulphoxide reacts diastereoselectively with imines to give chiral β-amino sulphoxides.