50798-95-3

Basic information

• Product Name: Benzenemethanamine, N-(3-chlorophenyl)-
• CAS NO: 50798-95-3
• Molecular Formula: C13H12ClN
• Molecular Weight: 217.698
• Mol File: 50798-95-3.mol
• Article Data: 79

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-(3-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-(3-chlorophenyl)-(50798-95-3)
• EPA Substance Registry System: Benzenemethanamine, N-(3-chlorophenyl)-(50798-95-3)

Safety Data

• Hazardous Substances Data: 50798-95-3(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 108-42-9 3-chloro-aniline 
• 100-52-7 benzaldehyde 
• 7519-65-5 N-(3-chlorobenzylidene)aniline 
• 108-88-3 toluene 
• 98-88-4 benzoyl chloride 
• 100-46-9 benzylamine 
• 121-73-3 3-Nitrochlorobenzene 
• 100-51-6 benzyl alcohol 
• 6004-21-3 3'-chloro-benzanilide 
• 625-99-0 3-iodochlorobenzene 
• 33558-28-0 N-Benzyl-N-(3-chloro-phenyl)-formamide 
• 73308-32-4 3-(3-Chloro-phenyl)-2,5-diphenyl-thiazolidin-4-one 
• 100-39-0 benzyl bromide 

Downstream Products

• 107931-51-1 7-chloro-2,4-diphenylquinoline 
• 138432-78-7 5-chloro-2,4-diphenylquinoline 
• 935733-34-9 1-benzyl-6-chloro-3-(1-hydroxyethylidene)indolin-2-one 
• 124069-97-2 N-Benzyl-N-(3-chloro-phenyl)-2-diazo-3-oxo-butyramide 
• 1438900-77-6 N⁴,N^4'-dibenzyl-2,2'-dichloro-[1,1'-biphenyl]-4,4'-diamine 
• 124070-04-8 1-(1-Benzyl-6-chloro-2-hydroxy-1H-indol-3-yl)-ethanone 
• 880256-26-8 2-{[benzyl-(3-chloro-phenyl)-carbamoyl]-methylene}-malonic acid diethyl ester 

Relevant articles and documents

Selective C-C bonds formation, N-alkylation and benzo[d]imidazoles synthesis by a recyclable zinc composite

Earth abundant metals are much less expensive, promising, valuable metals and could be served as catalysts for the borrowing hydrogen reaction, dehydrogenation and heterocycles synthesis, instead of noble metals. The uniformly dispersed zinc composites were designed, synthesized and carefully characterized by means of XPS, EDS, TEM and XRD. The resulting zinc composite showed good catalytic activity for the N-alkylation of amines with amines, ketones with alcohols in water under base-free conditions, while unsaturated carbonyl compounds could also be synthesized by tuning the reaction conditions. Importantly, it was the first time to realize the synthesis of 2-aryl-1H-benzo[d]imidazole derivatives by using this zinc composite under green conditions. Meanwhile, this zinc catalyst could be easily recovered and reused for at least five times.

COLORANT DISPERSION LIQUID AND PRINTING METHOD OF HYDROPHOBIC FIBER

PROBLEM TO BE SOLVED: To provide black dispersion liquid for inkjet printing ink that can manufacture a dyed thing excellent in color rendering, can obtain high quality dyed thing that can obtain high concentration dyed thing, and has excellent redispersion. SOLUTION: A colorant dispersion comprises (A) a compound expressed by a formula (1), and (B) polyoxyethylene arylphenyl ether-based dispersant and polyoxyethylene arylphenyl ether sulfate-based dispersant. (R1 is H or a nitro group; R2 and R3 are independently C1 to C4 alkoxy group or C1 to C4 alkyl group that may be substituted with a phenyl group; R4 is halogen atom; and R2 and R3 may be mutually coupled to form a ring.) SELECTED DRAWING: None COPYRIGHT: (C)2021,JPOandINPIT

Silver/manganese dioxide nanorod catalyzed hydrogen-borrowing reactions and tert-butyl ester synthesis

Silver/manganese dioxide (Ag@MnO2) nanorods are synthesized and characterized by scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, and X-ray photoelectron spectroscopy. It was discovered that Ag@MnO2 nanorods can realize hydrogen-borrowing reactions in high yields and are also effective for the synthesis of tert-butyl esters from aryl cyanides and tert-butyl hydroperoxide in a short period of time. Mechanistic experiments revealed that this catalytic system acts as a Lewis acid in hydrogen-borrowing reactions, while the synthesis of tert-butyl esters occurs through a radical pathway. This is the first report on the excellent catalytic activity of Ag@MnO2 nanorods as a catalyst.